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Effects of electrolyte pattern on mechanical and electrochemical properties of solid oxide fuel cells
Date
2012-09-01
Author
TİMURKUTLUK, BORA
Celik, Selahattin
Toros, Serkan
Timurkutluk, Cigdem
Mat, Mahmut D.
Kaplan, Yuksel
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In order to enhance the electrochemical performance and reduce the operation temperature of a conventional electrolyte supported solid oxide fuel cell (SOFC), a three layered electrolyte with various geometry is designed and fabricated. Novel three layered electrolytes comprise a dense and thin scandia alumina stabilized zirconia (ScAlSZ) electrolyte layer sandwiched between two hallow ScAlSZ electrolyte layers each having the same thickness as the support but machined into a filter like architecture in the active region with circular, rectangular and triangular cut off patterns. The percent of thin electrolyte layer in the active region is kept constant as 30% for all designs in order to investigate the effect of pattern geometry on the mechanical properties and the performance of the electrolytes. Single cells based on novel electrolytes are manufactured and electrochemical properties are evaluated. A standard electrolyte and electrolyte supported cell are also fabricated as a base case for comparison. Although the electrolyte having triangular patterns has the highest peak power at all operation temperatures considered, it exhibits the lowest flexural strength. (c) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Subject Keywords
Solid oxide fuel cell
,
Scandia alumina stabilized zirconia
,
Novel electrolyte design
,
Bending strength
URI
https://hdl.handle.net/11511/68256
Journal
CERAMICS INTERNATIONAL
DOI
https://doi.org/10.1016/j.ceramint.2012.04.008
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Unclassified, Article
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TİMURKUTLUK, BORA; Celik, Selahattin; Timurkutluk, Cigdem; Mat, Mahmut D.; Kaplan, Yuksel (2012-09-01)
Novel grate type electrolytes are designed and fabricated to improve the cell performance and to lower the operation temperature of intermediate temperature electrolyte supported solid oxide fuel cells based on scandium and ceria stabilized zirconia by partly reducing the electrolyte thickness. The characteristics of three different small size cells (11.62 cm(2) active area) having various electrolyte designs are investigated. A standard electrolyte supported cell is also produced as a base case for compari...
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B. TİMURKUTLUK, S. Celik, S. Toros, C. Timurkutluk, M. D. Mat, and Y. Kaplan, “Effects of electrolyte pattern on mechanical and electrochemical properties of solid oxide fuel cells,”
CERAMICS INTERNATIONAL
, pp. 5651–5659, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/68256.