SIMILARITIES AND DIFFERENCES IN COMPOSITIONS OFEASTERN AND WESTERN BLACK SEA AEROSOL

Date

2017-03-01

Author

Balcılar, İlker
Zararsız, Abdullah
Kalaycı, Yakup
Doğan, Güray
Tuncel, Süleyman Gürdal

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In this study daily aerosol samples were collected at two different sampling stations at the Black Sea Region of Turkey. Western Black Sea sampling station is located at the Bulgarian border of Turkey and approximately 50 km from the Black Sea coast. The station on the Eastern Black Sea is located at a high altitude site which is approximately 75 km from the Black Sea coast. Both stations are situated at relatively remote rural locations. Nearest large settlement area is at least 50 km away from both sites. At both sampling stations daily coarse (PM2.5-10) and fine (PM2.5) aerosol samples were collected on polycarbonate (Nuclepore) filters using Stacked Filter Units (SFU) between March 2011 and December 2012. Concentrations of eighteen elements were determined in collected aerosol samples by using an energy dispersive X-ray flurescence spectrometry. Measured concentrations of elements and ions varied between 0.46 ng m-3 for As and 2071 ng-3 for SO42- for Eastern Black Sea atmosphere and 0.6 ng m-3 for As and 3415 ng-3 for SO42- for Western Black Sea atmosphere. Concentrations of pollution derived elements were higher at the western part of the Black Sea, which is not surprising when the distribution of industrial sources around sampling location is considered. However, concentrations of some specific elements like Mn, Cr were higher at the Eastern part of the basin, due to emissions from smelters and metallurgical industries located at Georgia, Eastern part of Ukraine and central Russia. Besides the general evaluation of the elemental data also Factor Analysis (FA) was applied to the elemental data to characterize aerosols with respect to sources and to quantify the different sources and their importance for the composition of the aerosols at both Eastern and Western atmospheres

Subject Keywords

EDXRF, Aerosol, Trace elements, Western Black Sea, Eastern Black Sea

URI

https://hdl.handle.net/11511/80850

Journal

Fresenius Environmental Bulletin

Collections

Department of Environmental Engineering, Article

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SIMILARITIES AND DIFFERENCES IN COMPOSITIONS OF EASTERN AND WESTERN BLACK SEA AEROSOL Balcılar, İlker; ZARARSIZ, ABDULLAH; KALAYCI, YAKUP; DOĞAN, GÜRAY; Tuncel, Süleyman Gürdal (2017-01-01) In this study daily aerosol samples were collected at two different sampling stations at the Black Sea Region of Turkey. Western Black Sea sampling station is located at the Bulgarian border of Turkey and approximately 50 km from the Black Sea coast. The station on the Eastern Black Sea is located at a high altitude site which is approximately 75 km from the Black Sea coast. Both stations are situated at relatively remote rural locations. Nearest large settlement area is at least 50 km away from both sites....
Comparison of Source Regions Affecting SO42- and NO3- Concentrations at the Eastern Mediterranean and Black Sea Atmospheres Dogan, G.; GÜLLÜ, GÜLEN; Karakas, D.; Tuncel, G. (Bentham Science Publishers Ltd., 2010-01-01) In this study, source regions of atmospheric sulfate and nitrate in rural areas at the Black Sea and the Mediterranean coasts of Turkey are compared. Stations on the Black Sea and Mediterranean Sea are located at Amasra and Antalya regions, respectively. Source regions of SO42- and NO3- are determined by using potential source contribution function (PSCF). Statistical significance of source regions assigned by PSCF were assured using bootstrapping with 3000 iterations. Source regions affecting sulfate and n...
Comparison of sources affecting chemical compositions of aerosol and rainwater at different locations in Turkey Türküm, Ahmet; PEKEY, BEYHAN; PEKEY, HAKAN; Tuncel, Süleyman Gürdal (2008-09-01) In this study, concentrations of elements and ions were measured in atmospheric aerosol and rainwater samples collected at two rural stations on the Mediterranean and Black Sea coasts of Turkey. The relationship between chemical compositions of atmospheric aerosol and rainwater was investigated using receptor-oriented methods utilizing long-term data collected at the Antalya and Amasra stations in Turkey. Factor analysis performed on aerosol and rainwater data sets yielded that source types affecting chemic...
Chemical composition of Eastern Black Sea aerosol-Preliminary results BALCILAR, İLKER; Zararsız, Abdullah; Kalaycı, Yusuf; DOĞAN, GÜRAY; Tuncel, Süleyman Gürdal (2014-08-01) Trace element composition of atmospheric particles collected at a high altitude site on the Eastern Black Sea coast of Turkey was investigated to understand atmospheric transport of pollutants to this semi-closed basin. Aerosol samples were collected at a timber-storage area, which is operated by the General Directorate of Forestry. The site is situated at a rural area and is approximately 50 km to the Black Sea coast and 200 km to the Georgia border of Turkey. Coarse (PM2.5-10) and fine (PM2.5) aerosol sam...
The Use Of Back Trajectory Cluster Analysis Withpm2.5 Composition At The Eastern Black Sea Of Turkey Balcılar, İlker; Zararsız, Abdullah; Doğan, Güray; Tuncel, Süleyman Gürdal (2017-11-04) In this study, the influence of synoptic-scale atmospheric transport patterns on observed levels of trace elements at Eastern Black Sea region of Turkey was examined. Daily PM2.5 samples were collected at station (40°32’34”N, 39°16’57”E) on the Eastern Black Sea region of Turkey and collected samples were analyzed with ICP-MS for trace element composition. Five-day long back trajectories for March 2011 to December 2013 were calculated for 3 different arrival heights, 100m, 500m and 1500m, and combination of...

Citation Formats

İ. Balcılar, A. Zararsız, Y. Kalaycı, G. Doğan, and S. G. Tuncel, “SIMILARITIES AND DIFFERENCES IN COMPOSITIONS OFEASTERN AND WESTERN BLACK SEA AEROSOL,” Fresenius Environmental Bulletin, pp. 301–309, 2017, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/80850.