Polyhedral oligomeric silsesquioxanes appended conjugated soluble polymers based on thieno[3,4-c]pyrrole-4,6,dione acceptor unit

Date

2021-05-01

Author

Çakal, Deniz
Önal, Ahmet Muhtar

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A series of new donor-acceptor-donor type fluorescent molecules incorporating thieno[3,4-c]pyrrole-4,6-dione (TPD) as the acceptor unit were synthesized. TPD acceptor unit was modified with polyhedral oligomeric silsesquioxanes (POSS) cages and integrated with thiophene and alkylenedioxythiophene derivatives (3,4-ethylenedioxythiophene (EDOT) and 3,4-propylenedioxythiophene (ProDOT)) using Stille coupling reaction. The monomers, T-2-POSS, E-2-POSS, and P-2-POSS, were polymerized successfully via electrochemical and chemical polymerization techniques. As a fingerprint of D-A-D monomers, all monomers showed dual band characteristics due to intramolecular charge transfer. Soluble polymers exhibited reversible electrochromic responses electrochemically and chemically with fast switching times and high coloration efficiencies. E-2-POSS and its polymer PE2-POSS exhibited the lowest oxidation potential and band gap values as compared to their thiophene and ProDOT analogs. Also, P-2-POSS and its chemically obtained fluorescent polymer PP2-POSS-C represented high sensitivity towards Fe2+ and Fe3+ ions, which makes them potential candidates to be amenable for use in ion sensing. (C) 2021 Elsevier Ltd. All rights reserved.

Subject Keywords

Electrochromics, Polymerization, Thiophene

URI

https://hdl.handle.net/11511/90345

Journal

ELECTROCHIMICA ACTA

DOI

https://doi.org/10.1016/j.electacta.2021.138064

Collections

Department of Chemistry, Article

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Citation Formats

D. Çakal and A. M. Önal, “Polyhedral oligomeric silsesquioxanes appended conjugated soluble polymers based on thieno[3,4-c]pyrrole-4,6,dione acceptor unit,” ELECTROCHIMICA ACTA, pp. 0–0, 2021, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/90345.