A Nonionic Alcohol Soluble Polymer Cathode Interlayer Enables Efficient Organic and Perovskite Solar Cells

Date

2021-01-01

Author

Sharma, Anirudh
Singh, Saumya
Song, Xin
Rosas Villalva, Diego
Troughton, Joel
Corzo, Daniel
Toppare, Levent Kamil
Günbaş, Emrullah Görkem
Schroeder, Bob C.
Baran, Derya

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The choice of interfacial materials and their properties play a critical role in determining solar cell performance and stability. For compatibility with roll-to-roll printing, it is desirable to develop stable cathode interface layers (CILs) that can be processed over the photoactive layer using orthogonal solvents. In this study, an n-type naphthalene diimide core and oligo (ethylene glycol) side-chain-based conjugated polymer is reported as a universal, efficient CIL for organic and perovskite photovoltaics. Besides good thermal stability and easy processing in alcohol/water, the new CIL is found to possess electron transport properties with an electrical conductivity of 2.3 × 10-6 S cm-1, enabling its use as a CIL with a film thickness of up to ∼35(±2) nm. Utilizing the new CIL, 16% power conversion efficiency (PCE) is achieved for organic solar cells (OSCs) based on the PM6-Y6 photoactive layer (8.9% PCE for no CIL and 15.1% with state-of-the-art CIL, PDINO), and perovskite solar cells from methylammonium lead iodide yielded a PCE of 17.6%. Compared to the reference devices, the new CIL reduced trap-assisted carrier recombination and increased the built-in potential by 80 mV, simultaneously enhancing all photovoltaic parameters. Moreover, new CIL based devices had better photostability with no burn-in losses.

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85111312510&origin=inward
https://hdl.handle.net/11511/91522

Journal

Chemistry of Materials

DOI

https://doi.org/10.1021/acs.chemmater.1c01430

Collections

Department of Chemistry, Article

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Citation Formats

A. Sharma et al., “A Nonionic Alcohol Soluble Polymer Cathode Interlayer Enables Efficient Organic and Perovskite Solar Cells,” Chemistry of Materials, pp. 0–0, 2021, Accessed: 00, 2021. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85111312510&origin=inward.