Calculation of the T-X phase diagram for the first-order smectic-hexatic transitions in binary mixtures

Date

2022-04-01

Author

Kilit Dogan, E.
Yurtseven, Hasan Hamit

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This work gives the T-X phase diagram calculated from the Landau mean field model for the smectic-hexatic transitions in binary mixtures, particularly, in THI-13+THI-17. It is calculated near the SmC-SmF (Hex F)-Hex B triple point by considering transitions of SmC-SmF, SmF-HexB, and SmC-Hex B as the first order. The phase line equations are fitted to the experimental T-X phase diagram from the literature for this binary mixture by assuming the temperature and concentration dependence of the coefficients in the Landau free energy expansion. Calculations are given in some detail to describe the smectic-hexatic transitions in the THI-13+THI-17, which can also be considered for other binary mixtures under the Landau mean field model studied here.

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85128179628&origin=inward
https://hdl.handle.net/11511/97090

Journal

Physics of Fluids

DOI

https://doi.org/10.1063/5.0084526

Collections

Department of Physics, Article

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Citation Formats

E. Kilit Dogan and H. H. Yurtseven, “Calculation of the T-X phase diagram for the first-order smectic-hexatic transitions in binary mixtures,” Physics of Fluids, vol. 34, no. 4, pp. 0–0, 2022, Accessed: 00, 2022. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85128179628&origin=inward.