Double‐decker lutetium and europium phthalocyanine composites with reduced graphene oxide as supercapacitor electrode materials

Date

2022-12-01

Author

YABAŞ, EBRU
Biçer, Emre
Durukan, Mete Batuhan
Keskin, Deniz
Ünalan, Hüsnü Emrah

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© 2022 Elsevier B.V.Double‐decker phthalocyanines were synthesized by a classical method with phthalonitrile and lanthanide metal salts, europium and lutetium acetate. Non-covalent double-decker phthalocyanine-reduced graphene oxide (MPc2/rGO) composites were then prepared by simple sonication method. All the phthalocyanines were peripheral tetrasubstituted 5-(3-pyridyl)-1,3,4-oxadiazole. Following spectroscopic and morphological characterisation, fabricated composites were subjected to detailed electrochemical analysis. EuPc2/rGO and LuPc2/rGO composite electrodes showed specific capacitance values of 115 F/g and 86 F/g, respectively. Coulombic efficiency values for those materials were determined as 85% and 74%, respectively, at a significant current density of 5 A/g. Following 5000 cycles, EuPc2/rGO and LuPc2/rGO electrodes retained 93% and 99% of their initial capacitance, respectively. These results demonstrated the significant electrochemical performance of double-decker phthalocyanines and can be certainly extended to other metal salts or other composite formers with double-decker phthalocyanines.

Subject Keywords

Double-decker phthalocyanines, Europium, Lutetium, Nanocomposites, Supercapacitors

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85138522954&origin=inward
https://hdl.handle.net/11511/100827

Journal

Journal of Organometallic Chemistry

DOI

https://doi.org/10.1016/j.jorganchem.2022.122509

Collections

Department of Metallurgical and Materials Engineering, Article

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Citation Formats

E. YABAŞ, E. Biçer, M. B. Durukan, D. Keskin, and H. E. Ünalan, “Double‐decker lutetium and europium phthalocyanine composites with reduced graphene oxide as supercapacitor electrode materials,” Journal of Organometallic Chemistry, vol. 980-981, pp. 0–0, 2022, Accessed: 00, 2022. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85138522954&origin=inward.