On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene (HDC of TCE) Using Pd Supported on Swellable Organically Modified Silica (SOMS)

Date

2022-12-01

Author

Hunoor, Anagha
Ailawar, Saurabh
Rudzinski, Benjamin
Çelik, Gökhan
Burel, Laurence
Millet, Jean-Marc
Miller, Jeffrey T.
Edmiston, Paul L.
Ozkan, Umit S.

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https://hdl.handle.net/11511/101512

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27th North American Catalysis Society Meeting

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On the dual role of the reactant during aqueous phase hydrodechlorination of trichloroethylene (HDC of TCE) using Pd supported on swellable organically modified silica (SOMS) Ailawar, Saurabh; Hunoor, Anagha; Rudzinski, Benjamin; Çelik, Gökhan; Burel, Laurence; Millet, Jean-Marc; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S. (2021-08-01) Herein, the dual role of trichloroethylene (TCE) in liquid-phase hydrodechlorination with Pd catalysts supported on swellable organically modified silica (SOMS), is investigated. Batch experiments with TCE-soaked Pd/SOMS showed 45% higher conversion after 4 h than dry Pd/SOMS, suggesting that TCE acts as a reactant and as a swelling-agent. Flow experiments performed with and without ethanol (external swelling-agent) exhibited similar steady-state activities, confirming that TCE itself can cause swelling. Mo...
On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene Using Pd Supported on Swellable Organically Modified Silica Hunoor, Anagha; Ailawar, Saurabh; Rudzinski, Benjamin; Çelik, Gökhan; Burel, Laurence; Millet, Jean-Marc; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S. (2022-12-01)
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On the use of magnesium hydroxide towards halogen-free flame-retarded polyamide-6/polypropylene blends Balakrishnan, Harintharavimal; HASSAN, Azman; IŞITMAN, Nihat Ali; Kaynak, Cevdet (2012-08-01) Metal hydroxides have long been considered as abundant and low cost fillers towards the development of halogen-free flame-retarded polymers. In this study, magnesium hydroxide (MH) flame-retarded polyamide 6/polypropylene (PA6/PP) composites with various MH contents (20-50 wt%) were prepared and flame retardancy, thermal degradation, morphological, mechanical, thermal and thermo-mechanical characteristics were discussed. Mass loss calorimeter analysis revealed that the addition of MH provided improvements i...
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Citation Formats

A. Hunoor et al., “On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene (HDC of TCE) Using Pd Supported on Swellable Organically Modified Silica (SOMS),” presented at the 27th North American Catalysis Society Meeting, New York, Amerika Birleşik Devletleri, 2022, Accessed: 00, 2023. [Online]. Available: https://hdl.handle.net/11511/101512.