On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene Using Pd Supported on Swellable Organically Modified Silica

Date

2022-12-01

Author

Hunoor, Anagha
Ailawar, Saurabh
Rudzinski, Benjamin
Çelik, Gökhan
Burel, Laurence
Millet, Jean-Marc
Miller, Jeffrey T.
Edmiston, Paul L.
Ozkan, Umit S.

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https://hdl.handle.net/11511/101627

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AICHE 2021 Annual Meeting

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Department of Chemical Engineering, Conference / Seminar

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On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene (HDC of TCE) Using Pd Supported on Swellable Organically Modified Silica (SOMS) Hunoor, Anagha; Ailawar, Saurabh; Rudzinski, Benjamin; Çelik, Gökhan; Burel, Laurence; Millet, Jean-Marc; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S. (2022-12-01)
On the dual role of the reactant during aqueous phase hydrodechlorination of trichloroethylene (HDC of TCE) using Pd supported on swellable organically modified silica (SOMS) Ailawar, Saurabh; Hunoor, Anagha; Rudzinski, Benjamin; Çelik, Gökhan; Burel, Laurence; Millet, Jean-Marc; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S. (2021-08-01) Herein, the dual role of trichloroethylene (TCE) in liquid-phase hydrodechlorination with Pd catalysts supported on swellable organically modified silica (SOMS), is investigated. Batch experiments with TCE-soaked Pd/SOMS showed 45% higher conversion after 4 h than dry Pd/SOMS, suggesting that TCE acts as a reactant and as a swelling-agent. Flow experiments performed with and without ethanol (external swelling-agent) exhibited similar steady-state activities, confirming that TCE itself can cause swelling. Mo...
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Citation Formats

A. Hunoor et al., “On the Dual Role of the Reactant during Aqueous Phase Hydrodechlorination of Trichloroethylene Using Pd Supported on Swellable Organically Modified Silica,” presented at the AICHE 2021 Annual Meeting, 2022, Accessed: 00, 2023. [Online]. Available: https://hdl.handle.net/11511/101627.