Facile Synthesis and Origin of Enhanced Electrochemical Oxygen Evolution Reaction Performance of 2H-Hexagonal Ba2CoMnO6-delta as a New Member in Double Perovskite Oxides

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2022-12-06

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Erdil, Tuncay
Lökçü, Ersu
Yıldız, İlker
Okuyucu, Can
Kalay, Yunus Eren
Toparlı, Çiğdem

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Perovskite oxides have been considered promising oxygen evolution reaction (OER) electrocatalysts due to their high intrinsic activity. Yet, their poor long-term electrochemical and structural stability is still controversial. In this work, we apply an A -site management strategy to tune the activity and stability of a new hexagonal double perovskite oxide. We synthesized the previously inaccessible 2H-Ba2CoMnO6-delta (BCM) perovskite oxide via the universal sol-gel method followed by a novel air-quench method. The new 2H-BCM perovskite oxide exhibits outstanding OER activity with an overpotential of 288 mV at 10 mA cm-2 and excellent long-term stability without segregation or structural change. To understand the origin of outstanding OER performance of BCM, we substitute divalent Ba with trivalent La at the A-site and investigate crystal and electronic structure change. Fermi level and valence band analysis presents a decline in the work function with the Ba amount, suggesting a structure-oxygen vacancy-work function-activity relationship for BaxLa2-xCoMnO6-delta (x = 0, 0.5, 1, 1.5, 2) electrocatalysts. Our work suggests a novel production strategy to explore the single-phase new structures and develop enhanced OER catalysts.

URI

https://hdl.handle.net/11511/101768

Journal

ACS OMEGA

DOI

https://doi.org/10.1021/acsomega.2c05627

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Test and Measurement Center In advanced Technologies (MERKEZ LABORATUVARI), Article

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Citation Formats

T. Erdil, E. Lökçü, İ. Yıldız, C. Okuyucu, Y. E. Kalay, and Ç. Toparlı, “Facile Synthesis and Origin of Enhanced Electrochemical Oxygen Evolution Reaction Performance of 2H-Hexagonal Ba2CoMnO6-delta as a New Member in Double Perovskite Oxides,” ACS OMEGA, vol. 7, no. 48, pp. 44147–44155, 2022, Accessed: 00, 2023. [Online]. Available: https://hdl.handle.net/11511/101768.