Kinetic studies of heterocyclic amine ligand replacement reactions from some trans-dicyanobromoaminogold (III) comlexes

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1988

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Halabi, Nabil M

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https://hdl.handle.net/11511/13290

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Graduate School of Natural and Applied Sciences, Thesis

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Kinetic study of the reaction between hydroxyl-terminated polybutadiene and isophorone diisocyanate in bulk by quantitative FTIR spectroscopy Kincal, D; Özkar, Saim (Wiley, 1997-12-05) A kinetic study of the reaction between a hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) was carried out in the bulk state by using quantitative Fourier transform infrared(FTIR) spectroscopy. The reaction is shown to obey a second-order rate law, being first order in both the HTPB and IPDI concentrations. The activation parameters obtained from the evaluation of kinetic data are Delta H-double dagger = 41.1 +/- 0.4 kJ mol, Delta S-double dagger = -198 +/- 2 J K-1 mol(-1) and E-a...

Citation Formats

N. M. Halabi, “Kinetic studies of heterocyclic amine ligand replacement reactions from some trans-dicyanobromoaminogold (III) comlexes,” Middle East Technical University, 1988.