Synthesis of conducting copolymer of succinic acid bis-(pyrrolyl-phenyl) ester with thiophene

Ertaş, Merve


Synthesis and characterization of thiophen-3-yl-acetic acid 4-pyrrol-1-yl-phenyl ester and its conducting polymers
Bingöl, Bahar; Toppare, Levent Kamil; Department of Chemistry (2003)
Thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester (TAPE) monomer was synthesized by the reaction of thiophene acetic acid with thionyl chloride, and further reaction of thiophen-3-yl-acetyl chloride with 4-pyrrol-1-yl phenol. Electrochemical behavior of this monomer (TAPE) was determined by cyclic voltammetry. Homopolymers were achieved both by using electrochemical and chemical polymerization techniques. Copolymers of TAPE in the presence of bithiophene and pyrrole were synthesized by potentiostatic ele...
Synthesis and characterization of conducting copolymers of carboxylic acid multithiophene functionalized monomers
Bulut, Umut; Toppare, Levent Kamil; Department of Chemistry (2003)
Synthesis of 2-[(3-thienylcarbonyl)oxy]ethyl 3-thiophene carboxylate (TOET), 2,3-bis-[(3-thienylcarbonyl)oxy]propyl 3-thiophene carboxylate (TOPT), and 3-[(3-thienylcarbonyl)oxy]-2,2-bis{[(3-thienylcarbonyl)oxy]}propyl 3- thiophene carboxylate (TOTPT), and their copolymerization either with thiophene or pyrrole were achieved. The chemical structures of the monomers were investigated by Nuclear Magnetic Resonance Spectroscopy (NMR) and Fourier Transform Infrared Spectroscopy (FTIR). Electrochemical behavior ...
Preparation and characterization of butadiene-styrene and ethylene oxide-styrene block copolymers.
Orhan, Erdal H; Baysal, Bahattin; Department of Chemistry (1975)
Synthesis and characterization of conducting copolymers of menthyl ester of 3-thiophene acetic acid with pyrrole
Kiralp, S; Alkan, S; Toppare, Levent Kamil; Cianga, I; Yagci, Y (2003-01-01)
A new thiophene derivative containing menthyl group (MM) was synthesized and polymerized via chemical and electrochemical (constant current) methods. Polymers obtained and MM itself were used to synthesize copolymers with pyrrole under conditions of constant potential electrolyses. Cyclic voltammetry (CV), thermal analysis (DSC, TGA) and scanning electron microscopy (SEM) analyses were performed for the characterization of samples.
Investigation of copolymers of thiophene-functionalized polystyrene with pyrrole by pyrolysis mass spectrometry
Papila, Ozge; Toppare, Levent Kamil; Hacaloğlu, Jale (2006-06-01)
The thermal and structural characterization of electrochemically synthesized thiophene-functionalized polystyrene and pyrrole (PS/PPy) and their copolymers were investigated by direct pyrolysis mass spectrometry. The pyrolysis data confirmed the growth of polypyrrole onto the pendant thiophene moiety of polystyrene. It is determined that the electrolytic film has different properties from the mechanical mixture and the related homopolymers.
Citation Formats
M. Ertaş, “Synthesis of conducting copolymer of succinic acid bis-(pyrrolyl-phenyl) ester with thiophene,” M.S. - Master of Science, Middle East Technical University, 2003.