Use of clinoptilolite for copper and nickel removel from aqueous solutions

Download

index.pdf

Date

2006

Author

Çağın, Volkan

Metadata

Show full item record

Item Usage Stats

208
views

129
downloads

Heavy metals are well known toxic priority pollutants. Hence, wastewaters containing these species must be treated prior to discharge into receiving bodies. In this study, the potential of Bigadiç clinoptilolite for Cu2+ and Ni2+ removal from wastewaters was investigated in batch and continuous reactors. Results of the preliminary experiments revealed the optimum operating conditions, namely, initial solution pH of 5 and 4 for Cu2+ and Ni2+, respectively and contact time of 48 hours. Additionally, conditioning of clinoptilolite with 2M NaCl solution for 24 hours was found to considerably improve the capacity utilized at breakthrough. Maximum removal capacities and prevailing mechanisms in the system were investigated via equilibrium studies under preliminary determined optimum operating conditions. Langmuir and Freundlich models were fitted to the experimental data and Langmuir model was found to be better in describing the system behavior. Maximum removal capacities obtained from non-linear regression of Langmuir model are almost the same for Cu2+ and Ni2+ removal using as received clinoptilolite samples (0.31 and 0.32 meq/g respectively). However, conditioned clinoptilolite samples exhibit higher capacity for Cu2+ over Ni2+ (0.5 and 0.43 meq/g, respectively). Analyses of exchangeable cations in the aqueous phase were carried out to examine the prevailing mechanisms in the system. As a result, adsorption, dissolution of clinoptilolite and surface precipitation (particularly in the case of Cu2+ removal) are considered to accompany ion exchange. Finally, fixed-bed column studies were conducted with conditioned clinoptilolite samples for Cu2+ removal. An improvement in Cu2+ uptake was observed with decreasing volumetric flow rate (from 8 BV/h to 2-4 BV/h) and decreasing particle size (from 1.180-1.400 mm to 0.833-1.180 mm). Analyses of exchangeable cations as well as

Subject Keywords

Water Pollution.

URI

http://etd.lib.metu.edu.tr/upload/12606984/index.pdf
https://hdl.handle.net/11511/15713

Collections

Graduate School of Natural and Applied Sciences, Thesis

Suggestions

OpenMETU
Core

A chemical substitution study for a wet processing textile mill in Turkey Öztürk, Ertan; Demirer, Göksel Niyazi; Department of Environmental Engineering (2007) The main environmental concern in the textile industry is about the amount of water discharged and the chemical load it carries. The total quantity of chemicals used in textile mills varies from 10% to over 100% of the weight of the cloth produced. Many chemicals currently used in the textile industry affect the amount and the type of waste produced and their influence the aquatic life of the receiving stream. One of the critical steps in pollution prevention studies is auditing the use of chemicals and mak...
Determination of thmfp of the reservoirs in Turkey : kinetics aspect Artuğ, Mine; Dilek, Filiz Bengü; Department of Environmental Engineering (2004) Chlorine is still the most commonly used disinfectant in many water treatment plants all over the World. However, studies conducted demonstrated that the chlorine reacts with the natural organic matter (NOM) in source waters, and leads to the formation of a variety of chlorinated organic compounds, disinfection by-products (DBPs). Among these, the most common are the trihalomethanes (THMs). In this study, kinetics of the THM formation was investigated. Kinetic experiments were carried out with the raw water...
Use of laboratory-grown bacterial alginate in copper removal Moral, C. Kivilcimdan; Doğan, Özdemir; Sanin, Faika Dilek (IWA Publishing, 2012-01-01) Industrial production leads to toxic heavy metal pollution in water bodies. Copper is one of the examples that requires removal from effluents before being discharged. It is difficult and sometimes very expensive to remove toxic heavy metals by conventional treatment techniques. This study aims to remove copper by the use of bacterial alginate as a non-conventional technique. Bacterial alginates (natural polymers composed of mannuronic and guluronic acid monomers) were synthesized by Azotobacter vinelandii ...
Performance of ozone and peroxone on the removal of endocrine disrupting chemicals (EDCs) coupled with cost analysis Ölmez Hancı, Tuğba; Dogruel, S.; Emek, A. D. Allar; Yilmazer, C. Eropak; Cinar, S.; Kiraz, O.; Citil, E.; Orhon, A. Koc; Siltu, E.; Gucver, S. M.; Ozgun, O. Karahan; Tanık, Ayşe Gül; Yetiş, Ülkü (IWA Publishing, 2020-08-01) Micropollutants such as endocrine disruptors are one of the most important groups of chemicals polluting water resources. Conventional treatment systems may not be effective for the removal of endocrine disrupting chemicals (EDCs), and the fate of these chemicals should be carefully monitored in the effluent of wastewater treatment plants (WWTPs). Additional treatment methods such as advanced oxidation processes can be used for the removal of endocrine disruptors. This study presents the existence of endocr...
Decolorization of Synthetic Dye Solutions by Using Basaltic Tephra and Clinoptilolite Duygulu, Yusuf Bahadır; Atımtay, Aysel; Department of Environmental Engineering (2004) Discharge of colored effluents without decoloration originated from textile industries may cause serious problems in the receiving environments. In this study, natural materials that are basaltic tephra and clinoptilolite were used to remove various dyestuffs used in the textile industry. Those materials are cheap and available in large quantities in Turkey. The investigation of adsorption of basic, acidic and reactive dyes on these materials is the objective of this study. During preliminary experiments it...

Citation Formats

V. Çağın, “Use of clinoptilolite for copper and nickel removel from aqueous solutions,” M.S. - Master of Science, Middle East Technical University, 2006.