Behaviour of bentonite suspensions in non-aqueous media

Download
2006
Uskarcı, Togan
Bentonite is a smectite type clay mineral and swells in water. In this thesis, the effect of acetone, methyl-ethyl ketone, n-hexane on the properties of bentonite was determined by thermal analysis and water absorption tests. The tests indicated no significant change with treating bentonite with organic liquids. Because of the swelling property, only small amount of bentonite can be suspended in water. This may limit certain applications of bentonite. In this thesis, feasibility of suspending large quantities of bentonite in a non-aqueous media was studied. The concentrations for a pumpable high solid bentonite slurry were determined. As aqueous slurry showed pumpable properties up to 30-35 pounds/barrel, this concentration was as high as 125-150 pounds/barrel for acetone, 175-200 pounds/barrel for methyl-ethyl ketone and 325-350 pounds/barrel for n-hexane. Bentonite deposite has a complicated composition, containing free silica minerals, such as quartz, cristobalite, and opal; silicate minerals, such as feldspar, mica, and zeolite; carbonates or sulfates of alkaline earth metals, such as calcite, dolomite, and gypsum; and, in addition, iron compounds and humus. As mined it is primarily broken and dried and then pulverized by means of an attrition grinding machine. In this study dispersion of raw bentonite by high shear blending and shaking forces in the presence of acetone, methyl-ethyl ketone and n-hexane and eliminating the non-clay impurities by screening were studied. Many attempts have been made to provide a bentonite composition retaining the full swelling properties of the bentonite by the addition of non-aqueous liquids for obtaining a flexible waterproofing sheet. In this research the possible method for deposition of bentonite in a sponge by saturating the sponge with bentonite using organic liquids was investigated.

Suggestions

Study of adsorption characteristics of long chain alkyl amine and petroleum sulfonate on silicates by electrokinetic potential, microflotation, FTIR, and AFM analyses
ÖZÜN, Savaş; Atalay, M. Umit; Demirci, Şahinde (Informa UK Limited, 2019-05-19)
The long-chain alkyl amines and petroleum sulfonates are mostly used to remove unwanted minerals from feldspar ores in acidic pHs. In this study, their adsorption characteristics on pure albite and quartz were investigated by electrokinetic potential measurements, microflotation tests, Fourier transform infrared spectroscopy, and atomic force microscopy studies. According to the results, amine had strong influence on zeta potentials of both albite and quartz turning them positive and resulting over 90% flot...
Radiation-Induced Solid-State Polymerization of Allylthiourea and Crystal Structure Effects
Usanmaz, Ali; Yılmaz, Elvan (Informa UK Limited, 1987-5)
Allylthiourea crystals grown from water and from ethanol have been found to belong to the space groupP21/c and P21/m or related, respectively. The corresponding unit cell parameters are a = 13.45 Å, b = 17.33 Å,c = 14.38 Å, β = 96.6°, and d = 1.18g/cm3 for water-grown crystals, and a = 14.65 Å, b = 17.18 Å, c = 13.15 Å, β = 95.5°, and 1.17 g/cm3 for ethanol-grown crystals.
Crystallization field study for the formation of single phase sodium clinoptilolite: Batch composition, seed and temperature effects
Guevenir, O.; Kalıpçılar, Halil; Culfaz, A. (Wiley, 2009-03-01)
Although clinoptilolite is the most abundant zeolite mineral in nature, its synthesis under laboratory conditions has been difficult. A partial crystallization field study was done for the synthesis of clinoptilolite based on a nominal batch composition of 2.1Na(2)O:Al2O3:10Si(2)O:110H(2)O to delineate the limits of composition and temperature within which sodium clinoptilolite can be produced as a single phase in high yields. Effects of temperature, SiO2/Al2O3 molar ratio in the batch composition, and the ...
Distribution of tin in the northeastern Mediterranean
Yemeni̇ci̇ğlu, Semal; Saydam, Cemal; Sali̇hoğlu, İlkay (Elsevier BV, 1987)
Concentrations of tin, one of the naturally methylated elements, was determined in sea water, sediments and organisms, collected from the Northeastern Mediterranean. A hydride generation technique was employed, in which the tin and methyltin, were converted to their hydrides. The hydrides produced were detected by atomic absorption spectrophotometer. On the average, the inorganic tin content of sea water samples ranged between 1.1–236 ng/1. Although the dominant methyltin species was dimethyltin, all forms ...
Molecular characterization of acutely and gradually heavy metal acclimated aquatic bacteria by FTIR spectraoscopy
Kepenek, Eda S.; Gözen, Ayşe Gül; Severcan, Feride (Wiley, 2019-05-01)
In the environment, bacteria can be exposed to the concentration gradient of toxic heavy metals (gradual) or sudden high concentration of them (acute). In both situations, bacteria get acclimated to toxic heavy metal concentrations. Acclimation causes metabolic and molecular changes in bacteria. In this study, we aimed to understand whether there are differences between molecular profiles of the bacteria (Brevundimonas, Gordonia and Microbacterium) which are under acute or gradual exposure to cadmium or lea...
Citation Formats
T. Uskarcı, “Behaviour of bentonite suspensions in non-aqueous media,” M.S. - Master of Science, Middle East Technical University, 2006.