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Synthesis and electrochromic properties of conducting polymers of succinic acid bis-(2-thiophen-3-yl-ethyl) ester and their use in electrochromic devices
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Date
2006
Author
Saçan, Lale
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A new monomer; succinic acid bis-(2-thiophen-3-yl-ethyl)ester (SATE) was synthesized through the esterification reaction of 2-thiophen-3-yl-ethanol and succinyl chloride. The chemical structure of monomer was characterized via Nuclear Magnetic Resonance Spectroscopy (NMR) and Fourier Transform Infrared Spectroscopy (FTIR). Electrochemical behaviors of SATE alone and SATE in the presence of thiophene were studied by cyclic voltammetry (CV). The synthesis of homopolymer and copolymer were achieved via constant potential electrolysis. Both homopolymer (PSATE) and copolymer [P(SATE-co-Th)] were characterized by various techniques including cyclic voltammetry, FTIR, Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC), Thermal Gravimetry Analysis (TGA) and UV-VIS Spectrophotometer. Conductivities of samples were measured by four probe technique. The electrochromic properties of the polymers were investigated via spectroelectrochemistry, colorimetry and switching studies. In addition, dual type electrochromic devices (ECDs) composed of PSATE, P(SATE-co-Th) and poly(3,4-ethylenedioxythiophene) (PEDOT) were constructed and evaluated. Spectroelectrochemistry, switching ability and stability of the devices were investigated by UV-Vis Spectrophotometer and Cyclic Voltammetry. They have shown to possess good switching times, reasonable contrasts, high stabilities and optical memories.
Subject Keywords
Polymers.
,
Macromolecules.
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http://etd.lib.metu.edu.tr/upload/3/12607292/index.pdf
https://hdl.handle.net/11511/16315
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Graduate School of Natural and Applied Sciences, Thesis
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L. Saçan, “Synthesis and electrochromic properties of conducting polymers of succinic acid bis-(2-thiophen-3-yl-ethyl) ester and their use in electrochromic devices,” M.S. - Master of Science, Middle East Technical University, 2006.
