An experimental study on the performance of an adsorption cooling system and the numerical analysis of its adsorbent bed

Download
2011
Solmuş, İsmail
In this thesis, firstly, the equilibrium adsorption capacity of water on a natural zeolite at several zeolite temperatures and water vapor pressures has been experimentally determined for adsorption and desorption processes. Additionally, the modified Dubinin-Astakhov adsorption equilibrium model has been fitted to experimental data and separate correlations are obtained for adsorption and desorption processes as well as a single correlation to model both processes. Experimental results show that the maximum adsorption capacity of natural zeolite is nearly 0.12 kgw/kgad for zeolite temperatures and water vapor pressures in the range 40-150 C and 0.87-7.38 kPa. Secondly, a thermally driven adsorption cooling prototype using natural zeolite-water as working pair has been built and its performance investigated experimentally at various evaporator temperatures. Under the experimental conditions of 45 C adsorption, 150 C desorption, 30 C condenser and 22:5 C, 15 C and 10 C evaporator temperatures, the COP of the adsorption cooling unit is approximately 0.25 and the maximum average volumetric specific cooling power density (SCPv) and mass specific cooling power density (SCP) of the cooling unit are 5.2 kWm-3 and 7 Wkg-1, respectively. Thirdly, in order to investigate the dynamic heat and mass transfer behavior of the adsorbent bed of an adsorption cooling unit, a transient local thermal non equilibrium model that accounts for both internal and external mass transfer resistances has been developed using the local volume averaging method. Finally, the influence of several design parameters on the transient distributions of temperature, pressure and amount adsorbed inside the cylindrical adsorbent bed of an adsorption cooling unit using silica-gel/water have been numerically investigated for the one and two dimensional computational domains. Moreover, validity of the thermal equilibrium model assumption has been shown under the given boundary and design conditions. Generally, for the conditions investigated, the validity of the local thermal equilibrium and spatially isobaric bed assumptions have been confirmed. To improve the performance of the bed considered, e orts should be focused on reducing heat transfer resistances and intra-particle mass transfer resistances but not inter-particle mass transfer resistances.

Suggestions

Adsorption properties of a natural zeolite-water pair for use in adsorption cooling cycles
Solmus, Ismail; Yamali, Cemil; KAFTANOĞLU, BİLGİN; Baker, Derek Keıth; Caglar, Ahmet (2010-06-01)
The equilibrium adsorption capacity of water on a natural zeolite has been experimentally determined at different zeolite temperatures and water vapor pressures for use in an adsorption cooling system. The Dubinin-Astakhov adsorption equilibrium model is fitted to experimental data with an acceptable error limit. Separate correlations are obtained for adsorption and desorption processes as well as a single correlation to model both processes. The isosteric heat of adsorption of water on zeolite has been cal...
A two-energy equation model for dynamic heat and mass transfer in an adsorbent bed using silica gel/water pair
Solmus, Ismail; Rees, D. Andrew S.; Yamali, Cemil; Baker, Derek Keıth (2012-09-01)
In this study, the influence of the adsorbent bed dimensions, convective heat transfer coefficient between the cooling fluid and adsorbent bed and the thermal conductivity of the solid adsorbent material on the transient distributions of the solid and gas phase temperature difference, differences in the adsorbate concentration predicted by the instantaneous equilibrium and linear driving force (LDF) models, solid phase temperature, gas pressure and adsorbate concentration inside the adsorbent bed of a solid...
Elucidating the role of adsorption during artificial photosynthesis: H2O and CO2 adsorption isotherms over TiO2 reveal thermal effects under UV illumination
Üner, Deniz; Yılmaz, Begüm (2022-06-01)
Adsorption measurements of CO2 and H2O over TiO2 surfaces in dark and under illumination were carried out to reveal the ensuing bottlenecks of the initial steps of the artificial photosynthesis reaction. When the adsorption isotherms of both CO2 and H2O were measured under illumination, the results were comparable to isotherms measured at higher temperatures in dark. This evidence is interpreted as the presence of hot spots, due to charge carrier recombination reactions. Differential heat of adsorption meas...
A periodic DFT study of water and ammonia adsorption on anatase TiO2 (001) slab
Erdogan, Rezan; Ozbek, Olus; Önal, Işık (2010-06-15)
Water and ammonia adsorption mechanisms on anatase TiO2 (001) slab surface are investigated by means of periodic DFT approach. Molecular and dissociative adsorption energies for water are calculated to be -15 kcal/mol and -32 kcal/mol, respectively. Similarly, molecular and dissociative adsorption energies of ammonia on the same surface are found as 25 kcal/mol and 20 kcal/mol. A reverse result in this order is reached for the previous case of ONIOM cluster study (23 kcal/mol and 37 kcal/mol, respectively)....
A Numerical study of second order time stepping methods for the boussinesq equations
Demir, Medine; Kaya Merdan, Songül (null; 2018-10-21)
The Boussinesq approximation is a way to solve nonisothermall flow such as natural convection prob-lems, without having to solve for the full compressible formulation of the Navier-Stokes equations.Natural convection is related with an increasing number of fields including oceanography, meteorol-ogy and geophysical context [1, 2, 4]. Moreover, because of its presence both in nature and engi-neering applications, it has highly taken attention from academic societies. The accurate and efficientnumerical solu...
Citation Formats
İ. Solmuş, “An experimental study on the performance of an adsorption cooling system and the numerical analysis of its adsorbent bed,” Ph.D. - Doctoral Program, Middle East Technical University, 2011.