Investigation of properties of diesel water mixtures with and without emulsifier by terahertz spectroscopy

Download
2017
Çınar, Zühra
Additives such as alcohol, water are used in petroleum products for different purposes. Aim of the thesis is to determine water content in diesel water mixtures in THz region. The samples with and without emulsifier were analyzed in THz region. Besides, different kinds of oils (olive oil, sunflower oil, frying oil and engine grease #10) were measured in THz region because mixed of oils can be used instead of regular diesel. For this reason, we aimed to show distinguishability of regular diesel and mixed fuel. Then, FTIR spectrum of all diesel water mixtures and oils were collected in order to compare THz results. Meaningful results were obtained for diesel water mixtures by using both techniques. It has been shown that THz-TDS and FTIR are complementary techniques. However, FTIR was not a suitable technique for oils measurements because no marker could be seen to distinguish oils. On the other hand, THz-TDS was an effective technique because it enabled us to calculate refractive indexes of oils. When oils’ refractive indexes were compared, the differences between them could be seen clearly. These results gave a hint to us about distinguishability of diesel and mixed fuel by THz-TDS.

Suggestions

Characterization of biosurfectants enhancing kerosene degradation
Aydın, Dilan Camille; İçgen, Bülent (null; 2017-04-04)
Kerosene is a colorless flammable hydrocarbon liquid and it is obtained from the fractional distillation of petroleum [1]. It has numerous applications as fuel for jet engines, heating oil, solvent and insecticide [2]. Because of growing needs of kerosene production and extensive usage may end up with surface water contamination. Due to its high toxicity to biota, kerosene contamination requires remedial action to reduce environmental damage [3]. Biodegradation is an effective and eco-friendly method perfor...
A study of thin film solid phase microextraction methods for analysis of fluorinated benzoic acids in seawater
Boyacı, Ezel; Viteri, C. Ricardo; Pawliszyn, Janusz (2016-03-04)
Fluorinated benzoic acids (FBAs) are frequently used as tracers by the oil industry to characterize petroleum reservoirs. The demand for fast, reliable, robust, and sensitive approaches to separate and quantify FBAs in produced water, both in laboratory and field conditions, has not been yet fully satisfied. In this study, for the first time, thin film solid phase microextraction (TF-SPME) is proposed as a versatile sample preparation tool for the determination of FBAs in produced water by pursing two diffe...
Construction of amperometric biosensor modified with conducting polymer/carbon dots for the analysis of catechol
Yasa, Mustafa; Deniz, Aybuke; Forough, Mehrdad; Yildirim, Erol; Persil Çetinkol, Özgül; Udum, Yasemin Arslan; Toppare, Levent Kamil (Wiley, 2020-10-21)
Phenolic compounds used in food industries and pesticide industry, are environmentally toxic and pollute the rivers and ground water. For that reason, detection of phenolic compounds such as catechol by using simple, efficient and cost‐effective devices have been becoming increasingly popular. In this study, a suitable and a novel matrix was composed using a novel conjugated polymer, namely poly[1‐(5‐(4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b:4,5‐b']dithiophen‐2‐yl)furan‐2‐yl)‐5‐(2‐ethylhexyl)‐3‐(fu...
A study of steam-assisted gravity drainage performance in the presence of noncondensable gases
Canbolat, Serhat; Akın, Serhat; Kovscek, Anthony R. (null; 2002-12-01)
Traditionally, the addition of a non-condensable gas to steam is known to have a beneficial effect on heavy-oil production when conventional vertical wells are used. Little information and experimental evidence exists regarding the effect of the addition of such gases in the steam assisted gravity drainage (SAGD) process. The limited literature suggests that the addition of small amounts of such gases (e.g., carbon dioxide) may improve oil recovery. The gas accumulates at the top of the reservoir and provid...
Dielectric properties of fuel oils and their ethanol mixtures investigated by terahertz time-domain spectroscopy
Arık, Enis; Esentürk, Okan; Altan, Hakan; Department of Chemistry (2013)
The purpose of this study is to investigate the dielectric properties of fuel oils and their ethanol mixtures in the THz spectral region. We presented frequency dependent absorption coefficients, refractive indices, and dielectric constants calculated from the measurements of pure and mixtures of fuel oils. As the mixing ratio changes, meaningful shifts were observed in refractive index and absorption coefficient of the mixtures. For pure liquids, we used Debye model which provides a good estimate for the d...
Citation Formats
Z. Çınar, “Investigation of properties of diesel water mixtures with and without emulsifier by terahertz spectroscopy,” M.S. - Master of Science, Middle East Technical University, 2017.