Pyrolysis mass spectrometric analysis of styrene-butadiene block and random copolymers

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Date

1997-01-01

Author

Hacaloğlu, Jale
Ertugrul, Nergis
Fares, Muhammed M.
Suzer, Sefik

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rect pyrolysis mass spectrometric analysis of a styrene-butadiene-styrene block copolymer indicated that thermal decomposition of each block shows a resemblance to the related homopolymer, giving a possibility of differentiation of blocks. However, the random analog, the styrene butadiene rubber, degraded in a manner that is somewhat in between in nature of the thermal characteristics of both homopolymers. This technique shows promise to differentiate thermal behaviors of each sequence in block polymers if any exist. Indirect pyrolysis mass spectrometric analysis gave no clear evidence for differentiation of the nature and the composition of the copolymers.

Subject Keywords

Thermal-degradation, Inert atmosphere, Evolved-gas, Polybutadiene, Polystyrene, Polymers, Chromatography, Behavior

URI

https://hdl.handle.net/11511/30375

Journal

European Polymer Journal

DOI

https://doi.org/10.1016/s0014-3057(96)00068-7

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

J. Hacaloğlu, N. Ertugrul, M. M. Fares, and S. Suzer, “Pyrolysis mass spectrometric analysis of styrene-butadiene block and random copolymers,” European Polymer Journal, pp. 199–203, 1997, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/30375.