THERMAL POLYMERIZATION OF BIS(TRIHALOPHENOXO)COPPER(II) COMPLEXES IN EXCESS DIMETHYLFORMAMIDE AND DIMETHYL-SULFOXIDE AS LIGANDS

Date

1989-08-01

Author

KISAKUREK, D
SANLI, O

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Thermal decomposition of bis(trihalophenoxo)copper(II) complexes was achieved at 50°C in dimethylformamide or dimethyl sulfoxide. The resulting polymers, poly(oxydihalophenylene)s (2), were characterized by FTIR, 1H NMR and 13C NMR spectroscopy and by differential scanning calorimetry. The molecular weights were determined by the vapour pressure method. Tribrominated phenol derivatives prefer 1,4‐substitution, whereas with trichlorophenol derivatives 1,2‐and 1,4‐substitutions take place at equal rates in either solvent.

Subject Keywords

Polymer Science

URI

https://hdl.handle.net/11511/66011

Journal

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS

Collections

Department of Chemistry, Article

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Citation Formats

D. KISAKUREK and O. SANLI, “THERMAL POLYMERIZATION OF BIS(TRIHALOPHENOXO)COPPER(II) COMPLEXES IN EXCESS DIMETHYLFORMAMIDE AND DIMETHYL-SULFOXIDE AS LIGANDS,” MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, pp. 1843–1853, 1989, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66011.