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Sorption-Enhanced Reforming of Ethanol over Ni- and Co-Incorporated MCM-41 Type Catalysts
Date
2012-07-04
Author
Gunduz, Seval
Doğu, Timur
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Ni- and Co-incorporated MCM-41 type mesoporous materials with Ni/Si and Co/Si molar ratios of 0.12 were synthesized, characterized, and tested in both steam reforming of ethanol (SRE) and sorption-enhanced steam reforming of ethanol (SESRE) reactions. Characterization results showed that Co and Ni were successfully incorporated and well-dispersed in the mesoporous MCM-41 support. Ni- and Co-incorporated MCM-41 catalysts had surface area values of 449.0 and 303.6 m(2)/g, respectively. They also had narrow pore size distributions, with average pore diameters of 2.2 and 1.98 nm, respectively. SESRE results obtained with these catalysts showed that in situ capture of CO2 during ethanol reforming reaction significantly enhanced hydrogen yield in the temperature range of 500-600 degrees C. The catalytic performance of Ni-incorporated MCM-41 was much better than the Co-incorporated MCM-41, in hydrogen production by ethanol reforming. The highest hydrogen yield value obtained over the Ni-incorporated MCM-41 catalyst was achieved at 600 degrees C as 5.6 in SESRE reaction. This was similar to 94% of the maximum possible hydrogen yield value of 6.0.
Subject Keywords
Fuels
,
H-2 production
,
Hydrogen-production
,
Supported cobalt catalysts
URI
https://hdl.handle.net/11511/30648
Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
DOI
https://doi.org/10.1021/ie201852f
Collections
Graduate School of Natural and Applied Sciences, Article
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S. Gunduz and T. Doğu, “Sorption-Enhanced Reforming of Ethanol over Ni- and Co-Incorporated MCM-41 Type Catalysts,”
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
, pp. 8796–8805, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/30648.