Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Thickness effects in hydrogen sorption of Mg/Pd thin films
Date
2013-12-15
Author
Gharavi, Ayshe G.
Akyildiz, Hasan
Öztürk, Tayfur
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
205
views
0
downloads
Cite This
Mg thin films with various thicknesses ranging from 50 to 1000 nm capped with Pd have been prepared by thermal evaporation and their hydrogen sorption properties were examined following the electrical resistance change. The study showed that the hydrogenation and dehydrogenation temperatures correlate with the film thickness, thinner films reacting with hydrogen at reduced temperatures. It is concluded that films thinner than 200 nm react fully with hydrogen, while a considerable portion of the thicker films remain unreacted. The significance of this is discussed with reference to the design of hydrogen storage systems based on thin films or nanoparticles.
Subject Keywords
Magnesium thin films
,
Thermal evaporation
,
Hydrogen storage
,
Desorption temperature
URI
https://hdl.handle.net/11511/31598
Journal
JOURNAL OF ALLOYS AND COMPOUNDS
DOI
https://doi.org/10.1016/j.jallcom.2013.02.120
Collections
Graduate School of Natural and Applied Sciences, Article
Suggestions
OpenMETU
Core
Structural characteristics of thermally evaporated Cu0.5Ag0.5InSe2 thin films
Gullu, H. H.; Parlak, Mehmet (2016-05-01)
In this work, Cu0.5Ag0.5InSe2 (CAIS) thin film samples were prepared by thermal evaporation of Cu, Ag, InSe and Se evaporants sequentially on glass substrates. Following the deposition, annealing processes were applied at different temperatures. The as-grown and annealed CAIS samples were nearly stoichiometric in the detection limit of the compositional measurement. The x-ray diffraction (XRD) measurements revealed that they were in polycrystalline structure with a preferred orientation along the (112) dire...
Thickness effects in hydrogen sorption of magnesium/palladium thin films
Gharavi, Ayshe Gharemeshg; Öztürk, Tayfur; Department of Metallurgical and Materials Engineering (2012)
Magnesium (Mg) thin films with various thicknesses ranging from 50 to 1000 nm capped with nominally 20 nm Palladium (Pd) were prepared by a thermal evaporation unit. A total of 25 glass substrates were used in each experiment. The unit had a rotatable macro shutter, rectangular in shape, rotation axes opposite to the Mg source, which allowed controlled exposure of the substrates. Thin films of 50, 100, 150, 200, 300, 400, 500, 600, 800 nm and 1000 nm were produced in a single experiment. Hydrogenation and d...
Hydrogen absorption in magnesium based crystalline thin films
Akyildiz, Hasan; Ozenbas, Macit; Öztürk, Tayfur (2006-08-01)
A study is carried out for hydrogenation of Mg based thin films produced via thermal evaporation. Films produced were pure Mg, Mg capped with Au-Pd, Mg-Cu co-deposited and Mg-Cu multilayered. The films under the experimental conditions employed were crystalline with columnar grains with some degree of preferred orientation. In multi-component systems, the films in the as-deposited state were made of individual elements, but upon hydrogenation at temperatures greater than 473K, the elements react with each o...
Deposition of CZTSe thin films and illumination effects on the device properties of Ag/n-Si/p-CZTSe/In heterostructure
Bayrakli, O.; Terlemezoğlu, Makbule; GULLU, H. H.; Parlak, Mehmet (2017-06-30)
Characterization of Cu2ZnSnSe4 (CZTSe) thin films deposited by thermal evaporation sequentially from the pure elemental sources and in-situ post annealing was carried out at 400 C under Se evaporation atmosphere. Another annealing process was applied in nitrogen atmosphere at 450 degrees C to get poly-crystalline monophase CZTSe film structure. XRD analysis together with Raman spectroscopy was used to determine the structural properties. Spectral optical absorption coefficient evaluated from transmission da...
Fabrication of CdSexTe1-x thin films by sequential growth using double sources
Demir, Medine; Terlemezoglu, M.; Parlak, Mehmet (2021-10-15)
CdSexTe(1-x) (CST) ternary thin films were fabricated by stacking thermally evaporated CdSe and electron beam evaporated CdTe layers. The final structure was achieved in a stoichiometric form of approximately Cd:Se:Te = 50:25:25. The post-annealing processes at 300, 400, and 450 °C were applied to trigger the compound formation of CST thin films. The X-ray diffraction (XRD) profiles revealed that CdTe and CdSe have major peaks at 23.9° and 25.5° corresponds to (111) direction in cubic zinc-blend structure. ...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
A. G. Gharavi, H. Akyildiz, and T. Öztürk, “Thickness effects in hydrogen sorption of Mg/Pd thin films,”
JOURNAL OF ALLOYS AND COMPOUNDS
, pp. 0–0, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31598.