A novel silica trap for lead determination by hydride generation atomic absorption spectrometry

Date

2002-03-15

Author

Korkmaz, DK
Ertas, N
Ataman, Osman Yavuz

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A novel silica trap for lead determination at concentration levels of ng/l was developed using hydride-generation atomic absorption spectrometry. The device consists of a 7.0-cm silica tubing which is externally heated to a desired temperature. The lead hydride vapor is generated by a conventional hydride-generation flow system. The trap is placed between the gas-liquid separator and silica T tube; the device traps analyte species at 500 degreesC and releases them when heated further to 750 degreesC. The overall efficiency is 49%. The presence of hydrogen gas is required for revolatilization; O-2 gas must also be present. The analytical plot is linear up to 2.0 ng/ml for a collection period of 60 s. The response is also linear with respect to increasing collection periods up to 4 min. For 60-s trapping, the detection limit is 19 ng/l.

Subject Keywords

Hydride-generation atomic absorption spectrometry, Lead, Silica trap, On-line enrichment

URI

https://hdl.handle.net/11511/31698

Journal

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

DOI

https://doi.org/10.1016/s0584-8547(01)00379-2

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

D. Korkmaz, N. Ertas, and O. Y. Ataman, “A novel silica trap for lead determination by hydride generation atomic absorption spectrometry,” SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, pp. 571–580, 2002, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31698.