Sulfated Zirconia Modified SBA-15 Catalysts for Cellobiose Hydrolysis

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2011-01-01

Author

Yılmaz, Ayşen
Üner, Deniz
Yılmaz, Ayşen
van Santen, Rutger A.
Hensen, Emiel J. M.

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Zirconia modified SBA-15 becomes a very active catalyst for the selective hydrolysis of cellobiose to glucose after sulfation. Spectroscopic investigations indicate the presence of Bronsted acid sites with similar properties to those present in conventional sulfated zirconia. Indications are found that the sulfate groups attached to zirconia interact with silanol groups of SBA-15. The catalytic activity in cellobiose hydrolysis correlates well with results for temperature-programmed decomposition of i-propylamine for a range of sulfated ZrO2/SBA-15 catalysts. A glucose yield of 60% during cellobiose hydrolysis at a reaction time of 90 min at 160 degrees C is obtained.

Subject Keywords

Sulfated zirconia, Mesoporous, SBA-15, Cellobiose, Hydrolysis, Biomass

URI

https://hdl.handle.net/11511/32267

Journal

CATALYSIS LETTERS

DOI

https://doi.org/10.1007/s10562-010-0466-1

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Graduate School of Natural and Applied Sciences, Article

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Citation Formats

A. Yılmaz, D. Üner, A. Yılmaz, R. A. van Santen, and E. J. M. Hensen, “Sulfated Zirconia Modified SBA-15 Catalysts for Cellobiose Hydrolysis,” CATALYSIS LETTERS, pp. 33–42, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32267.