Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Interference effect of iron on the determination of gold in geological samples using the vapor generation technique and preconcentration in a graphite furnace
Date
2006-04-01
Author
Ertaş, Gülay
Ataman, Osman Yavuz
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
190
views
0
downloads
Cite This
A vapor generation procedure for the production of volatile species of An was studied using electrothermal atomic absorption spectrometry (ETAAS). The interference effects of iron in solution and in the gas phase in a quartz T-tube were studied for the first time in detail. A dual vapor generation system was used for a single heated quartz tube atomizer, so that it was possible to study interferences and classify them regarding their origins. Results show that both gas-phase and liquid-phase interferences are present. It was also concluded that since the total interference effect causes the An signal to be lower as compared to only the presence of gas-phase interactions in the experiment, the net liquid-phase interference from Fe should be suppressed. The method described in this study was used for the determination of gold in an ore reference material, Carlin Ore Mine, for the purpose of demonstrating the ability of the reported method to determine An without any extraction procedure.
Subject Keywords
Gold
,
Au
,
Iron
,
Fe
,
Electrothermal atomic absorption spectrometry
,
ETAAS
,
In situ trapping
,
Vapor formation
URI
https://hdl.handle.net/11511/32425
Journal
APPLIED SPECTROSCOPY
DOI
https://doi.org/10.1366/000370206776593618
Collections
Graduate School of Natural and Applied Sciences, Article
Suggestions
OpenMETU
Core
Electrothermal atomic absorption spectrometric determination of gold by vapor formation and in situ trapping in graphite tubes
Ertaş, Gülay; Ataman, Osman Yavuz (2004-10-01)
Gold was determined in ore samples following generation, separation, collection on a graphite cuvette inner wall, and atomization of its volatile species formed by combining an acidified sample solution with an aqueous sodium tetrahydroborate solution at room temperature. A detection limit of 2.6 mug L-1 (3sigma) was obtained with a 5.0 mL sample volume. Precision of replicate measurements was typically 10% RSD. The overall efficiency of the volatile species generation, transport, and trapping process was 0...
Thermal degradation of polystyrene composites. Part I. The effect of brominated polyepoxy and antimony oxide
Kaya, Hatice; Hacaloğlu, Jale (2014-01-01)
Thermal degradation of polystyrene (PS) involving brominated polyepoxy (BA) and antimony oxide (PS/BE/Sb2O3) was studied systematically via direct pyrolysis mass spectrometry. Thermal decomposition of brominated polyepoxy was started by loss of end groups. The relative yields of high mass thermal degradation products of PS and the product distribution of brominated polyepoxy and antimony oxide were changed noticeably during the pyrolysis of PS/BE/Sb2O3 composite. Its thermal decomposition was initiated by t...
Kinetic investigation of chemical vapor deposition of B4C on tungsten substrate
Karaman, Mustafa; Sezgi, Naime Aslı; Doğu, Timur; Ozbelge, H. Onder (2006-12-01)
Production of beta-rhombohedral boron carbide (B4C) on a tungsten substrate by the chemical vapor deposition from a BCl3-H-2-CH4 gas mixture was achieved. An impinging-jet reactor was used to minimize the mass-transfer limitations on the reaction kinetics, which made a detailed kinetic investigation possible. Results of the XRD and XPS analyses showed that the solid product formed on the substrate is a rhombohedral B4C phase. Both dichloroborane and boron carbide formation rates were found to increase with ...
Sorption of radioactive cesium and barium ions onto solid humic acid
Celebi, O.; Kilikli, A.; ERTEN, HASAN NİYAZİ (Elsevier BV, 2009-09-15)
In this study, the sorption behavior of two important fission product radionuclides ((137)Cs and (140)Ba) onto sodium form of insolubilized humic acid (INaA) were investigated as a function of time, cation concentration and temperature, utilizing the radiotracer method. The sorption processes are well described by both Freundlich and Dubinin-Radushkevich type isotherms. Thermodynamic constants such as: free energy (Delta G(ads)), enthalpy (Delta H(ads)), entropy (Delta S(ads)) of adsorption were determined....
Interference studies in slotted silica tube trap technique
Korkmaz, D; Mahmut, M; Helles, R; Ertas, N; Ataman, Osman Yavuz (2003-01-01)
Interference effects of KCl, NH4H2PO4, (NH4)(2)CO3, MgCl2, NH4NO3, NaNO3, (NH4)(2)SO4, MgSO4.7H(2)O, CaCl2, Ca(NO3)(2) and NaCl on Bi, Cd, In, Pb and Sb were investigated using the atom trapping technique with a double slotted silica tube. Analyte solutions at concentration levels of 60, 6, 300, 75, 100 ng mL(-1) for Bi, Cd, In, Pb and Sb, respectively, were aspirated into an air-acetylene flame and analyte species were collected on the silica surface. Revolatilization was effected by aspirating IBMK at the...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
G. Ertaş and O. Y. Ataman, “Interference effect of iron on the determination of gold in geological samples using the vapor generation technique and preconcentration in a graphite furnace,”
APPLIED SPECTROSCOPY
, pp. 423–429, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32425.