Sulfur speciation in the upper Black Sea sediments

Date

2010-01-30

Author

Yücel, Mustafa
Moore, Tommy S.
Janzen, Christopher P.
Luther, George W.

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

222
views

0
downloads

We report solid phase sulfur speciation of six cores from sediments underlying oxic, suboxic and anoxic-sulfidic waters of the Black Sea. Our dataset includes the five sulfur species [pyrite-sulfur, acid volatile sulfides (AVS), zerovalent sulfur (S(0)), organic polysulfides (RS(x)), humic sulfur] together with reactive iron and manganese, as quantified by dithionite extraction, and total organic carbon. Pyrite - sulfur was the major phase in all cores [200-400 mu mol (g dry wt)(-1)] except for the suboxic core. However, zerovalent sulfur and humic sulfur also reached very significant levels: up to about 109 and 80 mu mol (g dry wt)(-1), respectively. Humic sulfur enrichment was observed in the surface fluff layers of the eastern central basin sediments where Unit-1 type depositional conditions prevail. Elemental sulfur accumulated as a result of porewater sulfide oxidation by reactive iron oxides in turbidities from the anoxic basin margin and western central basin sediments. The accumulation of elemental sulfur to a level close to that of pyrite-S in any part of central Black Sea sediments has never been reported before and our finding indicates deep basin turbidites prevent the build-up of dissolved sulfide in the sediment. This process also contributes to diagenetic pyrite formation whereas in the non-turbiditic parts of the deep basin water column formed (syngenetic) pyrite dominates the sulfur inventory. In slope sediments under suboxic waters, organic sulfur (humic sulfur + organic polysulfides) account for 33-42% of total solid phase S, indicating that the suboxic conditions favor organosulfur formation. Our study shows that the interactions between depositional patterns (Unit 1 vs. turbidite), redox state of overlying waters (oxic-suboxic-sulfidic) and organic matter content determine sulfur speciation and enable the accumulation of elemental sulfur and organic sulfur species close to a level of pyrite-S.

Subject Keywords

Black Sea, Anoxic sediment, Sulfur, Iron, Elemental sulfur, Humic sulfur, Pyrite

URI

https://hdl.handle.net/11511/32667

Journal

CHEMICAL GEOLOGY

DOI

https://doi.org/10.1016/j.chemgeo.2009.10.010

Collections

Graduate School of Marine Sciences, Article

Suggestions

OpenMETU
Core

Earthquake-induced turbidite deposition as a previously unrecognized sink for hydrogen sulfide in the Black Sea sediments Yücel, Mustafa; Moore, Willard S. (2010-08-20) The depth profiles of excess Pb-210, Cs-137, elemental sulfur, reactive iron and porewater hydrogen sulfide of a western central basin sediment core in the Black Sea collectively point to the presence of a 20 cm thick reactive iron rich turbidite layer. This layer was most probably deposited there after the 1999 earthquakes in Northwestern Turkey, which caused oxidation of porewater hydrogen sulfide and anomalous accumulation of the product elemental sulfur in the solid phase.
Sulfur capture for fluidized-bed combustion of high-sulfur content lignites Altindag, H; Gogebakan, Y; Selçuk, Nevin (2004-12-01) Sulfur release and capture behavior of lignites with highly combustible sulfur-contents were investigated by extending a previously-developed comprehensive model to incorporate sulfur retention. The predictive performance of the model was tested by comparing the model predictions with on-line concentration measurements of O-2, CO2, CO and SO2. Favorable comparisons are obtained between the predicted and measured concentrations of gaseous species along the combustor. Results show that freeboard sulfur-captur...
Grain size distributions in airborne dust, river-suspended loads, and marine sediments from southeastern Turkey (NE Mediterranean Sea) Ediger, Vedat (2020-01-01) Between February 2001 and January 2002, near the coast of Erdemli, southeastern Turkey, 7 airborne dust samples, 7 coastal river-suspended sediment samples, and 3 marine sediment cores were collected. The main objective of this study was to understand the interrelationships among the multisources, multitransportation paths, and changing depositional conditions around the continental shelf of the Lamas River delta. In addition to a detailed study of satellite photos to track atmospheric dust in the region, g...
Recent sedimentation in the Black Sea: New insights from radionuclide distributions and sulfur isotopes Yücel, Mustafa; Butler, Ian B.; BOYCE, Adrian; Luther, George W. (2012-08-01) The Black Sea is the world's largest anoxic-sulfidic marine basin and has unique sedimentation conditions. Recent studies suggested that mass accumulation rates (MAR) in this environment have increased in the past century when compared to the last 2000 years (Unit 1 period). In this paper we test this hypothesis with new MAR data and further explore the relationship between the depositional pattern and pyrite-sulfur isotopic signature. Based on 15 cores sampled in 2001 and 2003, our dataset comprises radioa...
Spatial distribution and source identification of persistent organic pollutants in the sediments of the Yesilirmak River and coastal area in the Black Sea Dinc, Burak; ÇELEBİ, AHMET; Avaz, Gulsen; Canl, Oltan; Guzel, Baris; EREN, BEYTULLAH; Yetiş, Ülkü (2021-11-01) Surface sediments from the Yes,ilirmak River and the near coastal area in the Black Sea were collected using sediment traps to assess the spatial distributions of persistent organic pollutants and find their potential sources. Analyses were carried out to determine the concentrations of the persistent organic pollutants of seventeen polychlorinated dibenzo-p-dioxins and dibenzofurans, sixteen polycyclic aromatic hydrocarbons, seven polychlorinated biphenyls, and eight organochlorine pesticides using high-re...

Citation Formats

M. Yücel, T. S. Moore, C. P. Janzen, and G. W. Luther, “Sulfur speciation in the upper Black Sea sediments,” CHEMICAL GEOLOGY, pp. 364–375, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32667.