Skin-like self-assembled monolayers on InAs/GaSb superlattice photodetectors

Download
2012-09-12
Salihoglu, Omer
Muti, Abdullah
Kutluer, Kutlu
Tansel, Tunay
Turan, Raşit
AYDINLI, ATİLLA
We report on the effects of monolayer (ML) thick skin-like octadecanethiol (ODT, CH3[CH2](17)SH) on type-II InAs/GaSb MWIR photodetectors. Circumventing the ageing effects of conventional sulfur compounds, we use ODT, a self-assembling, long molecular chain headed with a sulfur atom. Photodiodes coated with and without the self-assembled monolayer (SAM) ODT were compared for their electrical and optical performances. For ODT-coated diodes, the dark current density was improved by two orders of magnitude at 77 K under -100 mV bias. The zero bias responsivity and detectivity were 1.04 A W (1) and 2.15 x 10(13) Jones, respectively, at 4 mu m and 77 K. The quantum efficiency was determined to be 37% for a cutoff wavelength of 5.1 mu m.
JOURNAL OF PHYSICS D-APPLIED PHYSICS

Suggestions

Solution processable donor acceptor type dibenzothiophen-S,S-dioxide derivatives for electrochromic applications
ÇAMURLU, PINAR; Durak, Tarik; Toppare, Levent Kamil (2011-10-15)
In this report, we highlight the synthesis and optical and electrochromic properties of dibenzothiophen-S,S-dioxide and 3-hexylthiophene based polymers. For this purpose a novel dibenzothiophen-S,S-dioxide and 3-hexylthiophene bearing, donor-acceptor-donor type monomer (THSO(2)) was synthesized through Stille cross-coupling reaction. THSO(2) was electrochemically polymerized in tetrabutylammonium hexafluorophosphate- dichloromethane couple. Furthermore, THSO(2) was subjected to electrochemical copolymerizat...
Bacterial anti-adhesive properties of a monolayer of zwitterionic block copolymer micelles
Hippius, Catharina; Butun, Vural; Erel Göktepe, İrem (Elsevier BV, 2014-08-01)
We report on bacterial anti-adhesive properties of a monolayer of block copolymer micelles (BCMs) with zwitterionic coronae and pH-responsive cores. BCMs were obtained by pH-induced self-assembly of selectively betainized poly[3-dimethyl (methacryloyloxyethyl) ammonium propane sulfonate-b-2-(diisopropylamino)ethyl methacrylate] (beta PDMA-b-PDPA) in aqueous solution above neutral pH. Monolayer films were self-assembled at pH 7.5 when beta PDMA-b-PDPA was in the micellar form. Bacterial anti-adhesive propert...
Tamoxifen-model membrane interactions: An FT-IR study
Boyar, H; Severcan, Feride (1997-06-01)
The temperature- and concentration-induced effects of tamoxifen (TAM) on dipalmitoyl phosphatidylcholine (DPPC) model membranes were investigated by the Fourier transform-infrared (FT IR) spectroscopic technique. An investigation of the C-H stretching region and the C=0 mode reveals that the inclusion of TAM changes the physical properties of the DPPC multibilayers by (i) shifting the main phase transition to lower temperatures; (ii) broadening the transition profile slightly; (iii) disordering the system i...
Multichromic benzimidazole-containing polymers: Comparison of donor and acceptor unit effects
Nurioglu, Ayda Goycek; Akpinar, Hava; Sendur, Merve; Toppare, Levent Kamil (2012-09-01)
This study reports a comparative study on electrochromic properties of two donoracceptordonor (DAD)-type polymers namely poly(2-heptyl-4,7-di(thiophen-2-yl)-1H-benzo [d]imidazole) (BImTh) and poly(4,7-bis(2,3-dihydrothieno[3,4-b] [1,4]dioxin-5-yl)-2-heptyl-1H-benzo[d]imidazole) (BImEd). DAD-type monomers were polymerized electrochemically on indium tin oxide-coated glass slides to determine the optical properties of the polymers. Electrochemical rho-doping experiments were performed to determine the band ga...
Poly(4-styrenesulfonic acid-co-maleic acid) stabilized cobalt(0) nanoparticles: A cost-effective and magnetically recoverable catalyst in hydrogen generation from the hydrolysis of hydrazine borane
Karahan, Senem; Özkar, Saim (2015-02-09)
Herein, we report the in situ generation, isolation and characterization of cobalt(0) nanoparticles, stabilized by poly(4-styrenesulfonic acid-co-maleic acid), PSSMA, and their catalytic activity in the hydrolysis of hydrazine borane (HB). Cobalt(0) nanoparticles having average particle size of 3.1 +/- 0.5 nm were prepared by in situ reduction of cobalt(II) chloride in aqueous solution of hydrazine borane in the presence of PSSMA, isolated magnetically from the catalytic reaction solution using a magnet, an...
Citation Formats
O. Salihoglu, A. Muti, K. Kutluer, T. Tansel, R. Turan, and A. AYDINLI, “Skin-like self-assembled monolayers on InAs/GaSb superlattice photodetectors,” JOURNAL OF PHYSICS D-APPLIED PHYSICS, pp. 0–0, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/33271.