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PFAM catalyzed enantioselective diethylzinc addition to imines
Date
2015-01-01
Author
Doğan, Özdemir
ÇAĞLI, EDA
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Chiral amines are important starting materials for the synthesis of biologically important compounds. Enantioselective addition of dialkylzinc reagents to imines is a reliable method for the synthesis of these compounds. Different chiral catalysts were developed and used for this method. Phosphorous based PFAM catalysts were tried for the first time in the enantioselective synthesis of amines by reacting diethylzinc with N-sulfonyl imines and N-diphenylphosphinoyl imines. Chiral amines were isolated with moderate to acceptable yields and enantioselectivities.
Subject Keywords
Chiral amines
,
Diethylzinc addition
,
Sulfonyl imines
,
Phosphinoyl imines
URI
https://hdl.handle.net/11511/34839
Journal
TURKISH JOURNAL OF CHEMISTRY
DOI
https://doi.org/10.3906/kim-1410-29
Collections
Department of Chemistry, Article