Synthesis of conducting graft copolymers of 2-(N-pyrrolyl)ethylvinyl ether with pyrrole

Date

2001-01-01

Author

Bengu, B
Toppare, Levent Kamil
Kalaycioglu, E

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2-(N-pyrrolyl)ethylvinyl ether (2-NEVE) was synthesized from 2-chloroethylvinyl ether (2-CEVE) via a phase catalysis reaction. Cyclic voltammetric studies were carried out to check for the electroactivity of 2-NEVE. Poly(2-(N-pyrrolyl)ethylvinyl ether) [poly(2-NEVE)] was synthesized via chemical methods. Graft copolymers of pyrrole and 2-NEVE were synthesized by electrochemical methods. The chemical structures of 2-NEVE and poly(2-NEVE) were investigated by several spectroscopic methods. Graft copolymers were characterized by means of FTIR, scanning electron microscopy (SEM). differential scanning calorimetry (DSC), and thermal gravimetric analysis (TGA). The conductivities of the graft copolymers were measured via a four-probe technique.

Subject Keywords

2-(N-pyrrolyl)-ethylvinyl ether, Pyrrole, Electrochemical polymerization, Block copolymers

URI

https://hdl.handle.net/11511/35174

Collections

Department of Chemistry, Article