Synthesis of ferrocenyl quinolines

2008-06-01
Zora, Metin
VELİOĞLU, Ozlem
A convenient one-pot synthesis of ferrocenyl-substituted quinolines via a molecular iodine-catalyzed reaction of ferrocenylimines with enolizable aldehydes is reported. First, nucleophilic addition of the in situ generated enol to ferrocenylimine produces beta-anilinopropionaldehyde, which then undergoes intramolecular Friedel-Crafts reaction to give dihydroquinoline derivative. Finally, subsequent dehydration and aerobic oxidation affords ferrocenyl quinolines.

Citation Formats
M. Zora and O. VELİOĞLU, “Synthesis of ferrocenyl quinolines,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 693, no. 12, pp. 2159–2162, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35243.