Synthesis of ferrocenyl pyrazoles by the reaction of 3-ferrocenylpropynal with hydrazinium salts

Date

2008-01-01

Author

Zora, Metin
Odabasoglu, Mustafa
Bueyuekguengoer, Orhan
Turgut, Guenseli

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Synthesis of ferrocenyl-substituted pyrazoles via the reaction between 3-ferrocenylpropynal and hydrazinium salts is described. Depending upon the substitution pattern of hydrazine derivative, the reaction affords 1-alkyl/aryl-5-ferrocenylpyrazoles and/or 1-alkyl/aryl-3-ferrocenylpyrazoles. Structures of 5-ferrocenyl-1-phenyl-1H-pyrazole, 1-benzyl-5-ferrocenyl-1H-pyrazole and 2-(3-ferrocenylpyrazol-1-yl)ethanol were identified by X-ray crystallography.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Materials Chemistry, Biochemistry

URI

https://hdl.handle.net/11511/47454

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY

DOI

https://doi.org/10.1016/j.jorganchem.2007.10.035

Collections

Department of Chemistry, Article

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Citation Formats

M. Zora, M. Odabasoglu, O. Bueyuekguengoer, and G. Turgut, “Synthesis of ferrocenyl pyrazoles by the reaction of 3-ferrocenylpropynal with hydrazinium salts,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp. 145–154, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/47454.