Pentacarbonyl(eta(2)-vinylferrocene)metal(0) complexes of Group 6 elements: synthesis and characterization

Date

2003-12-15

Author

Özkar, Saim
Demir, N

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Photolysis of hexacarbonylmetal(0) complexes of the Group 6 elements in the presence of vinylferrocene in an n-hexane solution at -15 degreesC yields pentacarbonyl (eta(2)-vinylferrocene)metal(0) complexes as the sole photo-substitution product, different from the general reaction pattern observed for the same Group 6 metal carbonyls with other olefins. M(CO)(5)(eta(2)-vinylferrocene) complexes (M = Cr, Mo, W) could be isolated from the solution and characterized by using spectroscopic techniques. The complexes were found to be not very stable and their stability increases in the order Cr < Mo < W. The relatively stable W(CO)(5)(eta(2)-vinylferrocene) could be isolated as-a pure solid and characterized by elemental analysis, MS, IR and NMR spectroscopy, while the solid samples of the less stable Cr(CO)(5)(eta(2)-vinylferrocene) and Mo(CO)(5)(eta(2)-vinylferrocene) complexes were found to be contaminated with free vinylferrocene and characterized only by using IR and NMR spectroscopy.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Materials Chemistry, Biochemistry

URI

https://hdl.handle.net/11511/35520

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY

DOI

https://doi.org/10.1016/j.jorganchem.2003.08.031

Collections

Department of Chemistry, Article

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Citation Formats

S. Özkar and N. Demir, “Pentacarbonyl(eta(2)-vinylferrocene)metal(0) complexes of Group 6 elements: synthesis and characterization,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp. 62–67, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35520.