Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Synthesis of star-shaped pyrrole and thiophene functionalized monomers and optoelectrochemical properties of corresponding copolymers
Date
2009-04-15
Author
Ak, Metin
Toppare, Levent Kamil
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
234
views
0
downloads
Cite This
Star-shaped thiophene and pyrrole functionalized monomers namely 2,4,6-tris(4-(1H-pyrrol-1-yl)phenoxy)-1,3,5-triazine (TriaPy) and 2,4,6-tris(4-(1H-pyrrol-1-yl)phenoxy)-1,3,5-triazine (TriaTh) were synthesized from 2,4,6-trichloro-1,3,5-triazine, thiophen-3-ylmethanol and 4-(1H-pyrrol-1-yl)phenol. Electrochemical copolymerization of monomers with thiophene and pyrrole was achieved in tetrabutylammonium tetrafluoroborate/acetonitrile (TBAFB/AN). Resulting copolymers were characterized by Fourier transform infrared (FTIR) spectrometer, cyclic voltammetry (CV) and conductivity measurements. Spectroelectrochemical analysis reflected that copolymer films have low lambda(max) for pi-pi* electronic transitions accompanied with a rather high band gap compared to polythiophene and polypyrrole. Switching abilities of copolymer films were evaluated by a kinetic study via measuring the transmittance (%T) at the maximum contrast.
Subject Keywords
General Materials Science
,
Condensed Matter Physics
URI
https://hdl.handle.net/11511/35608
Journal
MATERIALS CHEMISTRY AND PHYSICS
DOI
https://doi.org/10.1016/j.matchemphys.2008.10.041
Collections
Department of Chemistry, Article
Suggestions
OpenMETU
Core
Synthesis of aromatic poly(pyridinium salt)s and their electrochromic properties
Keshtov, M. L.; UDUM, YASEMİN; Toppare, Levent Kamil; Kochurov, V. S.; Khokhlov, A. R. (Elsevier BV, 2013-05-15)
Synthesis of a series of new conjugated electrochromic polymeric pyridinium salts containing main-chain triphenylamine and their electrochromic properties were demonstrated. All polymers exhibit intense UV absorptions at 336-338 nm in DMF and 340-343 nm in thin film form and fluorescence centered at 410-438 nm in DMF and 460-461 nm in thin film form. The electrochromic properties of the films were investigated by electrochemical and spectroelectrochemical methods. Reversible redox signals with stable electr...
Synthesis and characterization of a new soluble conducting polymer and its electrochromic device
Varis, Serhat; Ak, Metin; Tanyeli, Cihangir; Akhmedov, Idris Mecidoglu; Toppare, Levent Kamil (Elsevier BV, 2006-12-01)
A mixture of isomers 2,5-di(4-methyl-thiophen-2-yl)-1-(4-nitrophenyl)-1H-pyrrole, 2-(4-methyl-thiophen-2-yl)-5-(3-methyl-thiophen-2-yl)1-(4-nitrophenyl)-1H-pyrrole and 2,5-di(3-methyl-thiophen-2-yl)-1-(4-nitrophenyl)-1H-pyrrole (Me-SNS(NO2)) were synthesized. Resulting monomers were polymerized chemically, producing soluble polymers in common organic solvents. The average molecular weight has been determined by gel permeation chromatography (GPC) as Mn = 5.6 x 10(3) for the chemically synthesized polymer. T...
Synthesis of conducting copolymers of thiophene capped poly(ethylene oxide) with pyrrole and thiophene
Yildiz, Huseyin Bekir; Kiralp, Senem; Toppare, Levent Kamil; Yagci, Yusuf; Ito, Koichi (Elsevier BV, 2006-11-10)
Thiophene capped poly(ethylene oxide) (PEO) was synthesized. Copolymerisations of PEO with pyrrole (Py) and thiophene (Th) were achieved in water-sodium dodecyl sulfate (SDS) and acetonitrile (AN)-tetrabutylammonium tetrafluoroborate (TBAFB) solvent electrolyte couples via constant potential electrolyses. Characterisations of the samples were performed by NMR, cyclic voltammetry (CV), FT-IR, scanning electron microscopy (SEM). Electrical conductivities were measured by the four-probe technique. PEO-co-PTh f...
Synthesis and optical properties of fused aromatic thienopyrazine based pi-conjugated polymers
Kolay, Merve; Tarkuc, Simge; Udum, Yasemin Arslan; Toppare, Levent Kamil (IOP Publishing, 2011-07-01)
Two new polythieno[3,4-b]pyrazine derivatives, poly-10,12-bis(4-hexylthiophen-2-yl)dibenzo[f,h]thieno[3,4-b]quinoxaline (PDBTQ) and poly-8,10-bis(4-hexylthiophen-2-yl)acenaphtho[1,2-b]thieno[3,4-e]pyrazine (PATP) were synthesized by electrochemical polymerization and their electrochemical properties reported. Electroactivity of the monomer and electrochemical redox behavior of its polymers were investigated by cyclic voltammetry. Spectroelectrochemical analysis was performed and the band gaps of the polymer...
Synthesis of submicron silicalite-1 crystals from clear solutions
Kalıpçılar, Halil (Wiley, 2000-01-01)
Discrete and monodisperse submicron crystals of silicalite-l with a mean size of 0.3 mum were synthesized from clear crystallization solutions. The effects of silica content, alkalinity of batch and the nature of silica source on the product yield, crystal morphology and particle size distribution were investigated. The crystal shape was sphere-like or hexagonal twinned disks when silicic acid was the silica source. Change of silica source to sodium silicate solution leads to the formation of rounded-edged-...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
M. Ak and L. K. Toppare, “Synthesis of star-shaped pyrrole and thiophene functionalized monomers and optoelectrochemical properties of corresponding copolymers,”
MATERIALS CHEMISTRY AND PHYSICS
, pp. 789–794, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35608.