Removal of mercury from aqueous solutions via polymer-enhanced ultrafiltration

Date

1997-06-25

Author

Uludağ, Yusuf
Yılmaz, Levent

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

122
views

0
downloads

Separation of mercury from aqueous solutions by continuous polymer-enhanced ultrafiltration (PEUF) was investigated. Polyethyleneimine (PEI) was added to the solutions as the complexing agent before circulating the solution in a laboratory-scale continuous ultrafiltration system. Effects of mercury-to-polymer ratio, pressure drop and feed solution circulation rate on retention of mercury and permeate flux were studied. Constant retention values close to unity were obtained until a critical mercury-to-polymer ratio was exceeded. For higher metal loadings, retention values decreased linearly. Permeate flux increased linearly with pressure drop and was not affected by other parameters such as metal loading and feed circulation rate. Therefore, concentration polarization was not a problem for the studied range of variables.

Subject Keywords

Polymer metal complexation, Mercury separation, Ultrafiltration, Polyethyleneimine

URI

https://hdl.handle.net/11511/35828

Journal

JOURNAL OF MEMBRANE SCIENCE

DOI

https://doi.org/10.1016/s0376-7388(96)00342-0

Collections

Department of Chemical Engineering, Article

Suggestions

OpenMETU
Core

Removal of hexavalent chromium anions via polymer enhanced ultrafiltration using a fully ionized polyelectrolyte HAKTANIR, CEREN; Ozbelge, H. Onder; Bicak, Niyazi; Yılmaz, Levent (Informa UK Limited, 2017-01-01) A fully ionized polyelectrolyte was synthesized for Cr(VI) removal from aqueous solutions by continuous polymer enhanced ultrafiltration (PEUF). Effect of operating parameters such as pH, loading, polymer, and competing ion concentrations were examined. Highest Cr(VI) retention was obtained at a loading of 0.01 at pH 4. Increasing both polymer and chromate concentrations at a fixed loading of 0.01 decreased the retention which demonstrated the effect of crowding. In the presence of competing anions such as ...
Effect of operating parameters on selective separation of heavy metals from binary mixtures via polymer enhanced ultrafiltration Muslehiddinoglu, J; Uludağ, Yusuf; Ozbelge, HO; Yılmaz, Levent (Elsevier BV, 1998-03-18) Performance of continuous polymer enhanced ultrafiltration (PEUF) method was investigated for removal of mercury and cadmium from binary mixtures. This method includes the addition of polyethyleneimine (PEI) as a water soluble polymer to bind the metals, which was followed by ultrafiltration operation performed on both laboratory and pilot scale systems. The influence of various operating parameters such as temperature, metal/polymer ratio, presence of calcium ions and pH on retention of metals and permeate...
Separation of the protease enzymes of Bacillus licheniformis from the fermentation medium by crossflow ultrafiltration Takac, S; Elmas, S; Çalık, Pınar; Ozdamar, TH (2000-06-01) The separation from fermentation medium of extracellular serine alkaline protease (SAP) enzyme produced by Bacillus licheniformis was investigated using a crossflow ultrafiltration system. SAP was separated from the high molecular weight neutral protease (NP) and amylase (AMY) enzymes and from the low molecular weight organic acids and amino acids in a crossflow ultrafiltration system with 30000 Da and 10000 Da MWCO polysulfone membranes, respectively. The effects of transmembrane pressure (TMP), recirculat...
Employing Imino-Bis-Propane Diol Functional Polymers for Boron Removal from Geothermal Waters via Polymer Enhanced Ultrafiltration Zerze, Hasan; Ozbelge, H. Onder; Bicak, Niyazi; Yılmaz, Levent (2015-09-02) In this study, polymer enhanced ultrafiltration (PEUF) was used to remove boron from a geothermal water sample. The effect of co-ions such as chloride and sulfate on boron removal was investigated using previously synthesized poly (vinyl amino-N, N'-bis-propane diol) (GPVA) and its copolymers with DADMAC. The presence of co-anions and use of real waste water did not significantly reduce boron retentions and permeate fluxes. At optimum operating conditions 98% boron removal was achieved. It was demonstrated ...
Use of Specifically Tailored Chelating Polymers for Boron Removal from Aqueous Solutions by Polymer Enhanced Ultrafiltration Doganay, Ceren Oktar; Ozbelge, H. Onder; Bicak, Niyazi; AYDOĞAN, NİHAL; Yılmaz, Levent (Informa UK Limited, 2011-01-01) Two selective functional polychelatogens, namely hydroxyethylaminoglycerol functioned poly(glycidylmethacrylate (PNS) and Poly(4-Vinyl-1,3-dioxalan-2-one-co-vinyl acetate) (COP) were synthesized and utilized in polymer-enhanced ultrafiltration (PEUF) to remove boron from the aqueous solution. The effect of operating parameters on boron retention was investigated. PNS was synthesized in three molecular weights to observe the effect of molecular weight in borate retention. Increase in pH increased boron reten...

Citation Formats

Y. Uludağ and L. Yılmaz, “Removal of mercury from aqueous solutions via polymer-enhanced ultrafiltration,” JOURNAL OF MEMBRANE SCIENCE, pp. 93–99, 1997, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35828.