Effect of operating parameters on selective separation of heavy metals from binary mixtures via polymer enhanced ultrafiltration

Date

1998-03-18

Author

Muslehiddinoglu, J
Uludağ, Yusuf
Ozbelge, HO
Yılmaz, Levent

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

166
views

0
downloads

Performance of continuous polymer enhanced ultrafiltration (PEUF) method was investigated for removal of mercury and cadmium from binary mixtures. This method includes the addition of polyethyleneimine (PEI) as a water soluble polymer to bind the metals, which was followed by ultrafiltration operation performed on both laboratory and pilot scale systems. The influence of various operating parameters such as temperature, metal/polymer ratio, presence of calcium ions and pH on retention of metals and permeate flux was investigated. To investigate the possibility of selective separation of mercury and cadmium, experiments were conducted for binary solutions at different pH and loading ratios. It was seen that the retention of mercury decreased and permeate flux increased when the temperature increased. The increased pH and decreased metal/ polymer ratio, loading (L), resulted in higher retention of both metals. Shapes of retention vs. pH or L curves were very similar for both metals. Retentions stay almost constant at a value very close to unity until a critical L or pH value was reached, then, R decreases almost linearly with L or pH. However, retention of cadmium was affected more than that of mercury as the pH decreased and L increased. This leads to the selective separation of mercury and cadmium. At low pH values (about 5) and at high L values (about 0.3), mercury was removed by ultrafiltration operation while almost all cadmium passed through the membrane. At pH 5.5 and cadmium/polymer ratio about 0.35 and mercury/polymer ratio about 0.39, the highest separation factor was obtained as 49. (C) 1998 Elsevier Science B.V.

Subject Keywords

Physical and Theoretical Chemistry, Filtration and Separation, General Materials Science, Biochemistry

URI

https://hdl.handle.net/11511/48683

Journal

JOURNAL OF MEMBRANE SCIENCE

DOI

https://doi.org/10.1016/s0376-7388(97)00280-9

Collections

Department of Chemical Engineering, Article

Suggestions

OpenMETU
Core

Development of enhanced ultrafiltration methodologies for the resolution of racemic benzoin Olceroglu, Ayse Hande; Çalık, Pınar; Yılmaz, Levent (Elsevier BV, 2008-09-15) In the scope of achieving the separation of chiral molecules, enzyme enhanced ultrafiltration (EEUF), a new method based on polymer enhanced ultrafiltration (PEUF), utilizing apoenzymes as ligands, was developed. Benzoin was chosen as the model chiral molecule. Bovine serum albumin (BSA) and apo form of benzaldehyde lyase (BAL) (E.C. 4.1.2.38) were used as chiral ligands in PEUF and EEUF experiments, respectively. In order to bind to the target enantiomer well, the addition of ligand to the benzoin solution...
Use of Specifically Tailored Chelating Polymers for Boron Removal from Aqueous Solutions by Polymer Enhanced Ultrafiltration Doganay, Ceren Oktar; Ozbelge, H. Onder; Bicak, Niyazi; AYDOĞAN, NİHAL; Yılmaz, Levent (Informa UK Limited, 2011-01-01) Two selective functional polychelatogens, namely hydroxyethylaminoglycerol functioned poly(glycidylmethacrylate (PNS) and Poly(4-Vinyl-1,3-dioxalan-2-one-co-vinyl acetate) (COP) were synthesized and utilized in polymer-enhanced ultrafiltration (PEUF) to remove boron from the aqueous solution. The effect of operating parameters on boron retention was investigated. PNS was synthesized in three molecular weights to observe the effect of molecular weight in borate retention. Increase in pH increased boron reten...
Effect of molecular and electronic structure on the light-harvesting properties of dye sensitizers Mete, E.; Üner, Deniz; Cakmak, M.; Gulseren, O.; Ellialtoglu, S. (American Chemical Society (ACS), 2007-05-24) The systematic trends in structural and electronic properties of perylenediimide (PDI)-derived dye molecules have been investigated by DFT calculations based on the projector-augmented wave (PAW) method including gradient-corrected exchange-correlation effects. Time-dependent density functional theory (TDDFT) calculations have been performed to study the visible absorbance activity of these complexes. The effect of different ligands and halogen atoms attached to PDI were studied to characterize the light-ha...
Removal of hexavalent chromium anions via polymer enhanced ultrafiltration using a fully ionized polyelectrolyte HAKTANIR, CEREN; Ozbelge, H. Onder; Bicak, Niyazi; Yılmaz, Levent (Informa UK Limited, 2017-01-01) A fully ionized polyelectrolyte was synthesized for Cr(VI) removal from aqueous solutions by continuous polymer enhanced ultrafiltration (PEUF). Effect of operating parameters such as pH, loading, polymer, and competing ion concentrations were examined. Highest Cr(VI) retention was obtained at a loading of 0.01 at pH 4. Increasing both polymer and chromate concentrations at a fixed loading of 0.01 decreased the retention which demonstrated the effect of crowding. In the presence of competing anions such as ...
Estimation of Binding Constants of Cd(II), Ni(II) and Zn(II) with Polyethyleneimine (PEI) by Polymer Enhanced Ultrafiltration (PEUF) Technique Kadioglu, Sezin Islamoglu; Yılmaz, Levent; Ozbelge, H. Onder (Informa UK Limited, 2009-01-01) Continuous and batch processes of polymer enhanced ultrafiltration for the estimation of binding constants of divalent cadmium, nickel, and zinc ions have been elaborated. Polyethyleneimine was used as a complexation agent. Effect of pH and ionic strength on the binding ability of target metal ions to polyethyleneimine were estimated by continuous mode PEUF system. A mathematical model was developed to estimate apparent complexation constants of metal ions with PEI. The development of this model, which is i...

Citation Formats

J. Muslehiddinoglu, Y. Uludağ, H. Ozbelge, and L. Yılmaz, “Effect of operating parameters on selective separation of heavy metals from binary mixtures via polymer enhanced ultrafiltration,” JOURNAL OF MEMBRANE SCIENCE, pp. 251–266, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48683.