Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition

2011-01-01
Yurtseven, Hasan Hamit
Dildar, Yesin
We calculate the thermal expansion alpha(p), isothermal compressibility K-T and the specific heat, C-p-C-v as a function of pressure using the observed V-P data at room temperature close to the phase transition in CCl4. Calculated K-T, alpha(p) and C-p-C-v decrease as the pressure increases from phase III to phase IV in this molecular crystal system, as expected. On the basis of our calculations of the K-T, alpha(p) and C-p-C-v, the Pippard relations are established close to the III-IV phase transition in CCl4 which can be verified experimentally.

Citation Formats
H. H. Yurtseven and Y. Dildar, “Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition,” KOREAN JOURNAL OF CHEMICAL ENGINEERING, vol. 28, no. 1, pp. 252–255, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35893.