Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds

Doğan, Özdemir
Bulut, Adnan
Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc additions to aldehydes, diethylzinc additions to aldehydes, and Henry reactions. These reactions are summarized in this report.


Use of purified and modified bentonites in linear low-density polyethylene/organoclay/compatibilizer nanocomposites
Seyidoglu, Tijen; Yılmazer, Ülkü (2012-05-05)
Polyethylene-based ternary nanocomposites were prepared with different clay structures, obtained by the modification of purified Resadiye bentonite as the reinforcement, a random terpolymer of ethylene, butyl acrylate, and maleic anhydride with the trade name Lotader3210 as the compatibilizer, and linear low-density polyethylene (LLDPE) as the polymer matrix in an intensive batch mixer. The quaternary ammonium/phosphonium salts used for the modification of bentonite were dimethyldioctadecyl ammonium (DMDA) ...
Synthesis of New Thienylene Pyrrole Monomers and Their Electropolymerizations
Eken, Serap; Carbas, Buket Bezgin; Akdağ, Akın; Önal, Ahmet Muhtar (The Electrochemical Society, 2014-01-01)
In this study, four new 2,5-dithienylpyrroles (SNS) 1-(3-fluoro-phenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole (m-FPTP), 1-(3-chlorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole (m-ClPTP), 1-(3-bromo-phenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole (m-BrPTP) and 1-(4-bromo-phenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole (p-BrPTP) containing meta and para substituted benzene ring at the nitrogen atom were synthesized via Paal-Knorr condensation of 1,4-di(2-thienyl)-1,4-butanedione with corresponding halo-substituted anilines. The mon...
New route to synthesis of PVP-stabilized palladium(0) nanoclusters and their enhanced catalytic activity in Heck and Suzuki cross-coupling reactions
DURAP, FEYYAZ; Metin, Onder; AYDEMİR, MURAT; Özkar, Saim (2009-12-01)
Herein we report a new method for the synthesis and characterization of PVP-stabilized palladium(0) nanoclusters and their enhanced catalytic activity in Suzuki coupling and Heck reactions of aryl bromides with phenylboronic acid and styrene, respectively, under mild conditions. The PVP-stabilized palladium(0) nanoclusters with a particle size of 4.5 +/- 1.1 nm were prepared using a new method: refluxing a mixture of potassium tetrachloropalladate(II) and PVP in methanol at 80 degrees C for 1 h followed by ...
Application of L-prolinamides as highly efficient organocatalysts for the asymmetric Michael addition of unmodified aldehydes to nitroalkenes
Naziroglu, Hayriye Nevin; DURMAZ, MUSTAFA; Bozkurt, Selahattin; Demir, Ayhan Sıtkı; SIRIT, ABDULKADİR (2012-01-31)
The asymmetric Michael addition of aldehydes to nitroolefins was investigated using a combination of L-prolinamide derivatives and various acidic additives. (S)-1,1'-Bi-2-naphthol was found to be the most effective co-catalyst and afforded the nitroaldehyde products with excellent yields (up to 95%), enantiomeric excesses (up to 99%) and diastereoselectivity ratios (up to 99:1).
Incorporation of Different Conjugated Linkers into Low Band Gap Polymers Based on 5,6-Bis(octyloxy)-2,1,3 benzooxadiazole for Tuning Optoelectronic Properties
Goker, SEZA; HIZALAN, Gonul; KUTKAN, Seda; Udum, Yasemin Arslan; Çırpan, Ali; Toppare, Levent Kamil (2016-08-15)
Four new 2,1,3-benzooxadiazole-based donoracceptor conjugated polymers, namely poly{9-(9-heptadecanyl)-9H-carbazole-alt-5,6-bis(octyloxy)-4,7-di(selenophen-2-yl)benzo[ c][1,2,5] oxadiazole)}(PSBSC), poly{9-(9-heptadecanyl)-9H-carbazole- alt-5,6-bis(octyloxy)-4,7-di(furan-2-yl) benzo[c][1,2,5]oxadiazole)}(PFBFC), poly{9,9-dioctyl-9H-fluorene-alt-5,6bis( octyloxy)-4,7-di(selenophen-2-yl) benzo[c][1,2,5] oxadiazole)} (PSBSFL), and poly{9,9-dioctyl-9H-fluorene-alt-5,6-bis(octyloxy)- 4,7-di(furan-2-yl) benzo[c][...
Citation Formats
Ö. Doğan and A. Bulut, “Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds,” TURKISH JOURNAL OF CHEMISTRY, pp. 443–448, 2009, Accessed: 00, 2020. [Online]. Available: