Synthesis and Characterization of a New Conducting Polymer Based on 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-phthalonitrile

Date

2009-12-05

Author

Yavuz, Arzu
Bezgin, Buket
Önal, Ahmet Muhtar

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A new conducting polymer was synthesized by electrochemical polymerization of 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-2-phthalonitrile (SNS-PN). Electrochemical polymerization of SNS-PN was performed in acetonitrile/0.2M LiClO4 solvent/electrolyte couple. Characterizations of the resulting polymer P(SNS-PN) were carried out by cyclic voltammetry, UV-vis, and Fourier transform infrared (FTIR) spectroscopic techniques. Spectroelectrochemical studies revealed that P(SNS-PN) has an electronic band gap of 2.45 eV and exhibits electrochromic behavior. The switching ability of polymer was also monitored and the percentage transmittance change (Delta T%) was found as 24%. It is also found that P(SNS-PN) is fluorescent and its fluorescence intensity enhances in the presence of cations. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 2685-2690, 2009

Subject Keywords

Materials Chemistry, General Chemistry, Surfaces, Coatings and Films, Polymers and Plastics

URI

https://hdl.handle.net/11511/37576

Journal

JOURNAL OF APPLIED POLYMER SCIENCE

DOI

https://doi.org/10.1002/app.30269

Collections

Department of Chemistry, Article

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Citation Formats

A. Yavuz, B. Bezgin, and A. M. Önal, “Synthesis and Characterization of a New Conducting Polymer Based on 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-phthalonitrile,” JOURNAL OF APPLIED POLYMER SCIENCE, pp. 2685–2690, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37576.