Poly(ethylene terephthalate)/Carbon Nanotube Composites Prepared With Chemically Treated Carbon Nanotubes

Date

2011-07-01

Author

Yesil, Sertan
Bayram, Göknur

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

278
views

0
downloads

Surfaces of multiwalled carbon nanotubes (CNT) were functionalized by treatment with strong acid mixture (purification) followed by modification with sodium dodecyl sulfate, poly(ethylene glycol) (PEG), and diglycidyl ether of Bisphenol A (DGEBA). Poly(ethylene terephthalate) (PET)-based conductive polymer composites were prepared by using these CNT by means of melt mixing with a twin screw extruder. Amount of carboxylic acid groups on the CNT surface increased after acid treatment but decreased with surface modification due to the consumption of these groups during the chemical reactions between the surface modifiers and CNT surface. Fourier transformed infrared spectroscopy (FTIR) and nuclear magnetic resonance analyses of the composites revealed the increase in the interactions between PET and CNT surface after treatment with PEG and DGEBA. Mechanical strength of the composites prepared with modified CNT were higher than that of the untreated CNT-filled composite owing to the enhanced interactions between PET and CNT. POLYM. ENG. SCI., 51:1286-1300, 2011. (C) 2011 Society of Plastics Engineers

Subject Keywords

Materials Chemistry, General Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/37671

Journal

POLYMER ENGINEERING AND SCIENCE

DOI

https://doi.org/10.1002/pen.21938

Collections

Department of Chemical Engineering, Article

Suggestions

OpenMETU
Core

Polypyrrole grafts synthesized via electrochemical polymerization Balci, N; Toppare, Levent Kamil; Akbulut, Ural; Stanke, D; Hallensleben, ML (Informa UK Limited, 1998-01-01) Electrically conducting polypyrrole grafts with poly[(methyl meth acrylate)-co-(2-(N-pyrrolyl) ethyl methacrylate)] (PMMA-co-PEMA) were synthesized by constant potential electrolysis. Cyclic Voltammetry, DSC, TGA, SEM and elemental analysis were used in order to characterize the free standing films. Conductivities of the polymers were measured by a four-probe technique.
Microwave-assisted simultaneous synthesis of conducting, non-conducting and cross-linked polymers from sodium 2,4,6-tribromophenolate and LiOH Celik, Gueler Bayrakli; Kisakuerek, Duygu (Informa UK Limited, 2007-01-01) Poly(dibromophenylene oxide) (P) and conducting polymer (CP) and/or cross-linked polymer (CLP) were synthesized simultaneously from sodium 2,4,6-tribromophenol ate and LiOH by microwave energy in a very short time interval. Polymerizations were carried out (i) under constant microwave energy and constant amount of water with different time intervals ranging from I to 20 min, or (ii) at constant time intervals and constant amount of water with variation of microwave energy ranging from 90 to 900 W, or (iii) ...
Immobilization of Invertase in a Novel Proton Conducting Poly(vinylphosphonic acid) - poly(1-vinylimidazole) Network Isikli, Suheda; Tuncagil, Sevinc; Bozkurt, Ayhan; Toppare, Levent Kamil (Informa UK Limited, 2010-01-01) A novel proton conducting polymer blend was prepared by mixing poly(vinylphosphonic acid) (PVPA) with poly(1-vinylimidazole) (PVI) at various stoichiometric ratios via changing molar ratio of monomer repeating unit to achieve the highest protonation. The polymer network having the most suitable stoichiometric ratio for substantial proton conductivity was prepared and characterized by FT-IR spectroscopy and proton conductivity measurements. The network was used for immobilization of invertase and some import...
Conducting polymers of terepthalic acid bis-(2-thiophen-3-yl-ethyl) ester and their electrochromic properties Coskun, Y; Çırpan, Ali; Toppare, Levent Kamil (Elsevier BV, 2004-07-12) Terepthalic acid bis-(2-thiophen-3-yl-ethyl)ester (TATE) was synthesized through the reaction of 2-thiophen-3-yl-ethanol and terepthaloyl chloride. Homopolymer of TATE was synthesized via potentiostatic and potentiodynamic methods by using tetrabutylammonium tetrafluoroborate (TBAFB) as the supporting electrolyte in dichloromethane/borontrifluoride ethylether solvent mixture(DM/BFEE) (8:2, v/v). Copolymerisation of TATE with thiophene was achieved in DM/BFEE solvent mixture (8:2, v/v) by using TBAFB as the ...
Thermal degradation of poly(allyl methacrylate) by mass spectroscopy and TGA Vardareli, Tugba Kantav; Keskin, Selda; Usanmaz, Ali (Informa UK Limited, 2006-10-01) Allyl methacrylate, AMA was polymerized in CCl4 solution by alpha,alpha'-azoisobutyronitrile at 50 degrees C. The thermal degradation mechanism of PAMA was characterized by MS, TGA-FT-IR and FT-IR-ATR methods. The mass spectrum and TGA thermogram showed two stage degradation. The first stage of degradation was mostly linkage type degradation for the fragmentation of pendant allyl groups at 225 - 350 degrees C. In the second stage, at 395 - 515 degrees C, the degradation is random scission and depolymerizati...

Citation Formats

S. Yesil and G. Bayram, “Poly(ethylene terephthalate)/Carbon Nanotube Composites Prepared With Chemically Treated Carbon Nanotubes,” POLYMER ENGINEERING AND SCIENCE, pp. 1286–1300, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37671.