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ELECTROINITIATED POLYMERIZATION OF ACRYLONITRILE
Date
1988-01-01
Author
YURTTAS, B
Toppare, Levent Kamil
Akbulut, Ural
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Anionic polymerization of acrylonitrile was achieved by constant-potential electrolysis via direct electron transfer to the monomer. The reduction peak potential in the (C4 H9)4 NBF4 -CH3 CN electrolyte-solvent system was measured by cyclic voltammetry. On the other hand, dimethylformamide-metal salts were not found suitable for the direct electron-transfer process in our system. Polymers produced both anodically and cathodically were found to contain cyclized structures.
Subject Keywords
General Engineering
URI
https://hdl.handle.net/11511/37829
Journal
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY
DOI
https://doi.org/10.1080/00222338808051965
Collections
Department of Chemistry, Article