Soluble Alkyl Substituted Poly(3,4-Propylenedioxyselenophene)s: A New Platform For Optoelectronic Materials

Date

2011-10-15

Author

Atak, Samed
Icli-Ozkut, Merve
Önal, Ahmet Muhtar
CİHANER, ATİLLA

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Optical and electrochemical properties of regiosymmetric and soluble alkylenedioxyselenophene-based electrochromic polymers, namely poly(3,3-dibutyl-3,4-dihydro-2H-seleno pheno [3,4-b][1,4]dioxephine) (PProDOS-C(4)), poly(3,3-dihexyl-3,4-dihydro-2H-selenopheno[3,4-b][1,4]dioxephine) (PProDOS-C(6)), and poly(3,3-didecyl-3,4-dihydro-2H-selenopheno[3,4-b][1,4]dioxephine) (PProDOS-C(10)), are highlighted. It is noted that these unique polymers have low bandgaps (1.57-1.65 eV), and they are exceptionally stable under ambient atmospheric conditions. Polymer films retained 82-97% of their electroactivity after 5000 cycles. The percent transmittance of PProDOS-C(n) (n = 4, 6, 10) films found to be between 55 and 59%. Furthermore, these novel soluble PPro-DOS-C(n) polymers showed electrochromic behavior: a color change form pure blue to highly transparent state in a low switching time (1.0 s) during oxidation with high coloration efficiencies (328-864 cm(2) C(-1)) when compared to their thiophene analogues. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 4398-4405, 2011

Subject Keywords

Organic Chemistry, Materials Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/38201

Journal

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

DOI

https://doi.org/10.1002/pola.24880

Collections

Department of Chemistry, Article

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Citation Formats

S. Atak, M. Icli-Ozkut, A. M. Önal, and A. CİHANER, “Soluble Alkyl Substituted Poly(3,4-Propylenedioxyselenophene)s: A New Platform For Optoelectronic Materials,” JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, pp. 4398–4405, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38201.