MONOMER REACTIVITY RATIOS OF STYRENE-4-VINYLPYRIDINE COPOLYMERS AT LOW AND HIGH CONVERSIONS

Date

1993-01-01

Author

YILMAZ, E
KUCUKYAVUZ, Z

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Monomer reactivity ratios in free-radical copolymerization of styrene and 4-vinylpyridine monomers at 80-degrees-C in toluene solution under reduced pressure were determined for low and high conversions. Finemann-Ross, Kelen-Tudos, extended Kelen-Tudos and Mayo-Lewis methods were used for this purpose. The most reliable method was found to be the extended Kelen-Tudos method. By the use of this method, for conversions below 20%, monomer reactivity values of 0.700 +/- 0.005 and 0.335 +/- 0.001 were calculated for 4-vinylpyridine and styrene respectively. For conversions greater than 20%, these values were found to reduce to 0.538 +/- 0.004 and 0.277 +/- 0.001 respectively.

Subject Keywords

Organic Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/65822

Journal

POLYMER

DOI

https://doi.org/10.1016/0032-3861(93)90297-n

Collections

Department of Chemistry, Article

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Citation Formats

E. YILMAZ and Z. KUCUKYAVUZ, “MONOMER REACTIVITY RATIOS OF STYRENE-4-VINYLPYRIDINE COPOLYMERS AT LOW AND HIGH CONVERSIONS,” POLYMER, pp. 145–149, 1993, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/65822.