Synthesis, characterization and electrochromic properties of conducting copolymers of 3-[(3-thienylcarbonyl)oxy]-2,2-bis{[(3-thienylcarbonyl)oxy]}propyl 3-thiophene carboxylate with thiophene and pyrrole

2004-01-01
Bulut, U
Yilmaz, F
Yagci, Y
Toppare, Levent Kamil
3-[(3-Thienylcarbonyl)oxy]-2,2-bis{[(3-thienylcarbonyl)oxy]}propyl 3-thiophene carboxylate (TOTPT) was synthesized by the reaction of 3-thionylcarbonyl chloride with pentaerythritol, it was electrochemically polymerized with either thiophene or pyrrole by using tetrabutylammonium tetrafluoroborate (TBAFB) as the supporting electrolyte in acetonitrile (AN). Characterization of the resulting copolymers was carried out by FTIR spectroscopy, cyclic voltammetry, thermal gravimetry analysis (TGA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). Electrical conductivities of the copolymers were measured by the four-probe technique. The electrochemically synthesized copolymer was found to be capable of switching between an orange reduced state and a greenish-blue color oxidized state, and has an electronic band gap of 1.95 eV. The copolymer exhibited a long-term switching stability up to 400 double switches.
REACTIVE & FUNCTIONAL POLYMERS

Suggestions

Synthesis, characterization, and electrochromic properties of conducting copolymers of 2-[(3-thienylcarbonyl)oxy]ethyl 3-thiophene carboxylate with thiophene and pyrrole
Bulut, U; Alkan, S; Yilmaz, F; Yagci, Y; Toppare, Levent Kamil (Informa UK Limited, 2004-07-01)
2-[(3-Thienylcarbonyl)oxy]ethyl 3-thiophene carboxylate (TOET) was synthesized via the reaction of 3-thionylcarboxylic acid with ethylene glycol, and electrochemically polymerized with thiophene (Th) and pyrrole (Py) by using tetrabutylannnonium tetrafluoroborate (TBAFB) as the supporting electrolyte in acetonitrile (ACN). Characterization of the resulting copolymers were performed via cyclic voltammetry, FTIR, and scanning electron microscopy (SEM). Electrical conductivities are measured by the four-probe ...
Synthesis and characterization of conducting graft copolymers based on oligophenols
Sahmetlioglu, Ertugrul; Arikan, Ufuk; Toppare, Levent Kamil; Yuruk, Huseyin; Mart, Hasan (Informa UK Limited, 2006-10-01)
Oligo-2-aminophenol (OAF) was synthesized with oxidative polycondensation of 2-aminophenol and hydrogen peroxide in an aqueous alkaline medium at 80 degrees C. Oligo-2-aminophenol with thiophene side groups (TOAF) was obtained by the reaction of OAF and thiophene-3-acetic acid. Graft copolymers of TOAF and pyrrole were synthesized by electrochemical polymerization in p-toluene sulfonic acid (PTSA)/water medium. Characterization of the graft copolymer (TOAF-g-Py), was carried out by combination of techniques...
Synthesis and characterization of thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester and its conducting polymers
BINGÖL, Bahar; GÜNER, Yusuf; Çırpan, Ali; Toppare, Levent Kamil (Informa UK Limited, 2005-08-01)
Thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester (TAPE) monomer was synthesized via reaction of thiophen-3-yl acetyl chloride with 4-pyrrol-1-yl phenol. Homopolymers were achieved by using electrochemical and chemical polymerization techniques. Copolymers of TAPE with bithiophene or pyrrole were synthesized by potentiostatic electrochemical polymerization in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB) solvent-electrolyte couple. The chemical structures were confirmed by both Nuclear Magnet...
Synthesis and mesophase properties of block and random co-polymers of electroactive and liquid crystalline monomers
Yilmaz, F; Kasapoglu, F; Hepuzer, Y; Yagci, Y; Toppare, Levent Kamil; Fernandes, EG; Galli, G (Informa UK Limited, 2005-01-01)
Homo-polymers and random co-polymers of electroactive and liquid crystalline monomers, namely 3-thienylmethyl methacrylate (MTM) and 6-(4-cyanobiphenyl-4'-oxy)hexyl acrylate (LC6), were prepared by conventional free radical polymerization. Block co-polymers of MTM and LC6 were also synthesized by using the 1,1-diphenylethene (DPE) method. The obtained random and block co-polymers exhibited liquid crystal behavior depending on the content of the LC6 units. It was found that microphase separation of the polym...
Synthesis and characterization of poly(thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester-co-N-methylpyrrole) and its application in an electrochromic device
Bingol, B; Camurlu, P; Toppare, Levent Kamil (Wiley, 2006-05-05)
Copolymer of thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester (TAPE) with N-methylpyrrole (NMPy) was synthesized by potentiostatic electrochemical polymerization in acetotiitrile-tetrabutylammonium tetrafluoroborate solvent-electrolyte couple. The chemical structures were confirmed via Fourier transform infrared spectroscopy (FTIR), cyclic voltammetry (CV), and UV-vis spectroscopy. Electrochromic and spectroelectrochemical properties of poly(TAPE-co-NMPy) [P(TAPE-co-NMPy)] were investigated. Results sho...
Citation Formats
U. Bulut, F. Yilmaz, Y. Yagci, and L. K. Toppare, “Synthesis, characterization and electrochromic properties of conducting copolymers of 3-[(3-thienylcarbonyl)oxy]-2,2-bis{[(3-thienylcarbonyl)oxy]}propyl 3-thiophene carboxylate with thiophene and pyrrole,” REACTIVE & FUNCTIONAL POLYMERS, pp. 63–70, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38251.