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Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system
Date
2009-07-18
Author
Atilgan, Nurdan
Algi, Fatih
Önal, Ahmet Muhtar
CİHANER, ATİLLA
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A novel redox driven chemiluminescent material built on a terthienyl system, namely 5,7-di-ethylenedioxythiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (ETE-Lum), which is soluble in both organic media and basic aqueous solution was synthesized and characterized. Furthermore, its polymer, PETE-Lum, which is one of the most rare examples of chemiluminescent polymeric materials bearing a pyridazine unit, was obtained successfully by electrochemical means. Both of the materials give chemiluminescence either by treatment with oxidants (H2O2 and/or KMnO4) or by the application of a potential pulse.
Subject Keywords
Organic Chemistry
,
Biochemistry
,
Drug Discovery
URI
https://hdl.handle.net/11511/38551
Journal
TETRAHEDRON
DOI
https://doi.org/10.1016/j.tet.2009.05.019
Collections
Department of Chemistry, Article
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N. Atilgan, F. Algi, A. M. Önal, and A. CİHANER, “Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system,”
TETRAHEDRON
, pp. 5776–5781, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38551.