NO oxidation and NOx storage over Ce-Zr mixed oxide supported catalysts

Caglar, B.
Üner, Deniz
NO oxidation and NO storage behavior of 1% Pt/10% BaO/CexZr1-xO2 (x=0, 0.25, 0.5, 0.75, 1) catalysts prepared by the Pechini method were investigated via Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) spectroscopy. DRIFTS study revealed that in the presence of Pt/BaO/Ce0.5Zr0.5O2, NO is oxidized to NO2 in the absence of gas phase O-2 at room temperature due to high oxygen mobility in the support material.


In situ DRIFTS characterization of wet-impregnated and sol-gel Pd/TiO 2 for NO reduction with CH4
Karakaş, Gürkan; Ozkan, Umit S. (Elsevier BV, 2002-05-01)
The adsorption/desorption behavior of 2%Pd/TiO2 catalysts synthesized by wet-impregnation and modified sol–gel techniques were examined in NO–CH4–O2 reaction using in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The catalyst prepared by the modified sol–gel method showed significantly higher resistance toward oxygen while maintaining a 100% NO conversion. Under NO+CH4+O2 flow, the main adsorbed NO species was identified as the linearly adsorbed NO on metallic palladium (Pd0–NO)...
The role of alkali-metal promotion on CO oxidation over PdO/SnO2 catalysts
MİRKELAMOĞLU, BURCU; Karakaş, Gürkan (Elsevier BV, 2006-01-17)
Sol-gel prepared PdO/SnO2 and Na-PdO/SnO2 catalysts were investigated by X-ray photoelectron spectroscopy (XPS), diffuse reflectance IR (DRIFTS), temperature-programmed reaction spectroscopy (TPRS) and impulse techniques. Alkali-metal promotion was observed to enhance CO oxidation rate and decreases light-off temperatures of PdO/SnO, XPS analysis revealed that alkali-metal promotion resulted in the segregation of Pd atoms and promoted the oxygen storage capacity of the catalysts. The presence of super-oxide...
Inverse relation between the catalytic activity and catalyst concentration for the ruthenium(0) nanoparticles supported on xonotlite nanowire in hydrogen generation from the hydrolysis of sodium borohydride
Akbayrak, Serdar; Özkar, Saim (Elsevier BV, 2016-12-01)
Ruthenium(0) nanoparticles supported on xonotlite nanowire (Ru(0)/X-NW) were prepared by the ion exchange of Rua* ions with Ca2+ ions in the lattice of xonotlite nanowire followed by their reduction with sodium borohydride in aqueous solution at room temperature. Ru(0)/X-NW show high catalytic activity and long life time in hydrogen generation from the hydrolysis of sodium borohydride with a turnover frequency value up to 305 min(-1) and a total turnover number of 63,100 mol H-2/mol Ru in hydrogen generatio...
Effect of hydrogen ion-exchange capacity on activity of resin catalysts in tert-amyl-ethyl-ether synthesis
Boz, N; Doğu, Timur; Murtezaoglu, K; Dogu, G (Elsevier BV, 2004-08-10)
Activities of ion-exchange resin catalysts, having different hydrogen exchange capacities ranging between 5.1 and 1.3 meq H+/g, on the etherification reactions of 2M1B (2-methyl-1-butene) and 2M2B (2-methyl-2-butene) with ethanol were experimentally tested in a fixed bed reactor. These catalysts were prepared by the heat treatment of Amberlyst-15 catalysts at 220 degreesC at different durations of time and also by the synthesis of sulfonated styrene divinyl benzene cross-linked resins. Activity of these cat...
Intrazeolite cobalt(0) nanoclusters as low-cost and reusable catalyst for hydrogen generation from the hydrolysis of sodium borohydride
Rakap, Murat; Özkar, Saim (Elsevier BV, 2009-09-07)
Intrazeolite cobalt(0) nanoclusters were prepared by ion-exchange of Co2+ ions with the extraframework Na+ ions in the zeolite-Y followed by the reduction of Co2+ ions in the supercages of zeolite-Y with sodium borohydride at room temperature. The intrazeolite cobalt(0) nanoclusters were isolated as solid materials and characterized by ICP-OES, XRD, HRTEM, SEM, XPS, Raman spectroscopy and N-2 adsorption technique. The catalytic activities of intrazeolite cobalt(0) nanoclusters in the hydrolysis reaction of ...
Citation Formats
B. Caglar and D. Üner, “NO oxidation and NOx storage over Ce-Zr mixed oxide supported catalysts,” CATALYSIS COMMUNICATIONS, pp. 450–453, 2011, Accessed: 00, 2020. [Online]. Available: