Quinoxaline derivatives as long wavelength photosensitizers in photoinitiated cationic polymerization of diaryliodonium salts

Date

2012-02-01

Author

Bulut, Umut
Kolay, Merve
Tarkuc, Simge
Udum, Yasemin Arslan
Toppare, Levent Kamil

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The present paper is focused on visible light initiated cationic polymerizations. Photoinitiated polymerization of representative vinyl ether and oxirane monomers using two quinoxaline derivatives; namely (2-(2,3-dihydrobenzo [b][1,4]dioxin-6-yl)-3-(2,3-dihydrobenzo[b]-[1,4]dioxin-7-yl)-5-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-8-(2,3-dihydrothieno[3,4-b][1,4]dioxin-7yl) quinoxaline) (DBQEd) and 2,3,5,8-tetra(thiophen-2-yl)quinoxaline (TTQ) are studied. Novel dyes based on the quinoxaline skeleton are employed as efficient photosensitizers in cationic photopolymerizations. Polymerizations were initiated at room temperature upon irradiation with long-wavelength UV and visible lights in the presence of diphenyliodonium hexafluorophosphate (Ph(2)1(+)PF(6)(-)). The progress of the polymerizations was monitored by optical pyrometry (OP). Solar irradiation is also employed to carry out the cationic polymerization of a diepoxide monomer in the presence of air.

Subject Keywords

Cationic polymerization, Diaryliodonium salts, Photopolymerization, Photosensitization, Photosensitizers, Quinoxaline derivatives

URI

https://hdl.handle.net/11511/39939

Collections

Department of Chemistry, Article