A novel integrated process for the functionalization of methane and ethane: bromine as mediator

Date

2004-11-24

Author

Lorkovic, IM
Yılmaz, Ayşen
Yilmaz, GA
Zhou, XP
Laverman, LE
Sun, SL
Schaefer, DJ
Weiss, M
Noy, ML
Cutler, CI
Sherman, JH
McFarland, EW
Stucky, GD
Ford, PC

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We describe a novel, integrated multi-step process for the partial oxidation of alkanes to alcohols, ethers or olefins using O-2 as oxidant. The sequential transformations are (1) alkane bromination to alkyl bromide(s) and HBr, (2) reaction of this mixture with solid metal oxide (MO) to neutralize the HBr and to generate oxygenated products or olefins plus solid metal bromide, and (3) oxidation of the spent solid with 02 to regenerate the metal oxide and Br-2 for reuse.

Subject Keywords

General Chemistry, Catalysis

URI

https://hdl.handle.net/11511/40181

Journal

CATALYSIS TODAY

DOI

https://doi.org/10.1016/j.cattod.2004.07.058

Collections

Department of Chemistry, Article

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Citation Formats

I. Lorkovic et al., “A novel integrated process for the functionalization of methane and ethane: bromine as mediator,” CATALYSIS TODAY, pp. 317–322, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/40181.