Mechanism of TAME and TAEE synthesis from diffuse-reflectance FTIR analysis

Date

2005-02-28

Author

Boz, N
Doğu, Timur
Murtezaoglu, K
Dogu, G

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This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

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Diffuse-reflectance FTIR results obtained with tert-amyl-methyl-ether (TAME), ethanol, methanol, i-amylenes and mixtures of i-amylenes with alcohols supported a Langmuir-Hinshelwood type reaction mechanism involving adsorbed i-amylene molecules, which form a bridged structure between the adsorbed alcohols and the -SO3H sites of Amberlyst-15. Number of available sites involved in the adsorption of i-olefins is drastically decreased with an increase in alcohol concentration. The reaction rate model, which was proposed basing on the DRIFTS results, was shown to give good agreement with the published initial rate data for TAEE synthesis. The rate of tert-amyl-ethyl-ether (TAEE) formation was found to give a rather sharp maximum at an ethanol activity smaller than 0.1.

Subject Keywords

General Chemistry, Catalysis

URI

https://hdl.handle.net/11511/62951

Journal

CATALYSIS TODAY

DOI

https://doi.org/10.1016/j.cattod.2004.09.074

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

N. Boz, T. Doğu, K. Murtezaoglu, and G. Dogu, “Mechanism of TAME and TAEE synthesis from diffuse-reflectance FTIR analysis,” CATALYSIS TODAY, pp. 419–424, 2005, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62951.