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CORRELATION OF ANODIC PEAK POTENTIALS WITH THE SEMI-EMPIRICAL ORBITAL AND HOMO ENERGIES OF VARIOUS VINYL COMPOUNDS

1989-03-24
YILMAZ, H
YURTSEVER, E
Toppare, Levent Kamil
The anodic peak potentials, Ep,a of various monomers were measured by cyclic voltammetry. The measurements were made in an acetonitrile + tetrabutylammonium fluoroborate system versus a Ag0Ag+ (0.01 M) reference electrode. The measured potentials were correlated to π-orbital energies and HOMO energies computed by the semi-empincal MNDO method. A linear correlation was found.