CORRELATION OF THE ANODIC PEAK POTENTIALS WITH THE QUANTUM-MECHANICAL PROPERTIES OF VARIOUS VINYL COMPOUNDS

Date

1987-11-25

Author

YILMAZ, H
Toppare, Levent Kamil
YURTSEVER, E

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The anodic peak potentials, Ep,a of various vinyl compounds were measured by cyclic voltammetry. The measurements were made in the acetonitrile-tetrabutylammonium fluoroborate system versus a Ag0Ag+ (0.01 M) reference electrode. The measured potentials were correlated to π-orbital energies and bond orders calculated by semi-empirical SCF MO methods. A linear correlation was obtained.

Subject Keywords

Analytical Chemistry, Electrochemistry, General Chemical Engineering

URI

https://hdl.handle.net/11511/43253

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

DOI

https://doi.org/10.1016/0022-0728(87)85232-4

Collections

Department of Chemistry, Article

Citation Formats

H. YILMAZ, L. K. Toppare, and E. YURTSEVER, “CORRELATION OF THE ANODIC PEAK POTENTIALS WITH THE QUANTUM-MECHANICAL PROPERTIES OF VARIOUS VINYL COMPOUNDS,” JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol. 237, no. 2, pp. 187–190, 1987, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/43253.