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CORRELATION OF THE ANODIC PEAK POTENTIALS WITH THE QUANTUM-MECHANICAL PROPERTIES OF VARIOUS VINYL COMPOUNDS
Date
1987-11-25
Author
YILMAZ, H
Toppare, Levent Kamil
YURTSEVER, E
Metadata
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This work is licensed under a
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The anodic peak potentials, Ep,a of various vinyl compounds were measured by cyclic voltammetry. The measurements were made in the acetonitrile-tetrabutylammonium fluoroborate system versus a Ag0Ag+ (0.01 M) reference electrode. The measured potentials were correlated to π-orbital energies and bond orders calculated by semi-empirical SCF MO methods. A linear correlation was obtained.
Subject Keywords
Analytical Chemistry
,
Electrochemistry
,
General Chemical Engineering
URI
https://hdl.handle.net/11511/43253
Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
DOI
https://doi.org/10.1016/0022-0728(87)85232-4
Collections
Department of Chemistry, Article