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Convenient synthesis of multivalent zinc(II)-dipicolylamine complexes for molecular recognition
Date
2013-02-01
Author
Xiao, Shuzhang
Türkyılmaz, Serhan
Smith, Bradley D.
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A pair of novel dipicolylamine ligands bearing isothiocyanate groups were used as conjugation reagents to prepare multivalent molecules with anionic recognition capability. The isothiocyanates were reacted with two classes of dendritic scaffolds bearing primary amines, squaraine rotaxanes, and PAMAM dendrimers, and the products were converted into water soluble zinc(II) coordination complexes. The multivalent squaraine rotaxanes exhibit high fluorescence quantum yields in water and are very well suited for biological imaging applications.
Subject Keywords
Dendrimer
,
Fluorescence
,
Squaraine rotaxane
,
Zinc dipicolylamine
,
Multivalent
URI
https://hdl.handle.net/11511/41298
Journal
TETRAHEDRON LETTERS
DOI
https://doi.org/10.1016/j.tetlet.2012.11.103
Collections
Department of Chemistry, Article
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S. Xiao, S. Türkyılmaz, and B. D. Smith, “Convenient synthesis of multivalent zinc(II)-dipicolylamine complexes for molecular recognition,”
TETRAHEDRON LETTERS
, pp. 861–864, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/41298.