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Band gap and refractive index tunability in thallium based layered mixed crystals
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Date
2015-07-21
Author
Hasanlı, Nızamı
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Compositional variation of the band gap energy and refractive index of TlMeX2-type (Me = Ga or In and X = S or Se) layered mixed crystals have been studied by the transmission and reflection measurements in the wavelength range of 400-1100 nm. The analysis of absorption data of TlGa1-xInxSe2, TlGa(S1-xSex)(2), TlGa1-xInxS2, and TlIn(Se1-xSx)(2) mixed crystals revealed the presence of both optical indirect and direct transitions. It was found that the energy band gaps of mixed crystals decrease at the replacing of gallium atoms by indium and of sulfur atoms by selenium ones. Through the similar replacing of atoms (smaller atoms by larger ones) in the studied mixed crystals, the refractive index shows the quite opposite behavior. (C) 2015 AIP Publishing LLC.
Subject Keywords
Ellipsometry
,
Tlgase2
,
Optical-absorption
,
Lattice-parameters
,
Electrical-properties
,
Dielectric-properties
,
Interband-transitions
,
Tlins2 single-crystals
,
Isomorphic atom substitution
,
Equal-to 1
URI
https://hdl.handle.net/11511/42093
Journal
JOURNAL OF APPLIED PHYSICS
DOI
https://doi.org/10.1063/1.4926864
Collections
Department of Physics, Article
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The optical properties of Tl2InGaS4 layered single crystals have been studied by means of transmission and reflection measurements in the wavelength range of 400-1100 nm. The analysis of the room temperature absorption data revealed the presence of both optical indirect and direct transitions with band gap energies of 2.35 and 2.54 eV, respectively. Transmission measurements carried out in the temperature range of 10-300 K revealed that the rate of change of the indirect band gap with temperature is gamma =...
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The optical properties of Tl2InGaSe4 layered single crystals have been studied through the transmission and reflection measurements in the wavelength range of 500-1100 nm. The analysis of room temperature absorption data revealed the presence of both optical indirect and direct transitions with band gap energies of 1.86 and 2.05 eV, respectively. Transmission measurements carried out in the temperature range of 10-300 K revealed that the rate of change of the indirect band gap with temperature is gamma = -4...
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N. Hasanlı, “Band gap and refractive index tunability in thallium based layered mixed crystals,”
JOURNAL OF APPLIED PHYSICS
, pp. 0–0, 2015, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42093.